Orientation Dependence of Photoelectron Angular Distribution in Nitrogen Molecule Irradiated by XUV Laser Field

We theoretically study the dependence of photoelectron angular distribution on laser polarization direction in nitrogen molecules. The approach is based on the time-dependent density functional theory at the level of local density approximation complemented by self-interaction correction. It is found that photoelectron emission in one photon regime could be considered as a probing tool for the main character of different types of molecular orbitals (\sigma or \pi). The pattern of emitted photoelectrons strongly depends on the polarized angle of the laser, for \sigma orbital, the number of photoelectron decreases with increasing the polarized angle, while for \pi orbital, it has the inverse relation to the polarized angle, which reveals the multi-electron effect in molecules. On the other hand, concerning the total photoelectron emission, one should take into account a few occupied orbitals instead of only the outmost one.