Effect of Low Diffusion Coefficient on Eutectic Instability of Al-25wt%Sm Alloy

  • Received Date: April 16, 2008
  • Published Date: October 31, 2008
  • Diffusion coefficient decides the solute diffusion length and is a critical parameter in the selection of microstructure scales and in governing microstructure transitions. Al-25wt%Sm alloy is selected to reveal the impact of low diffusion coefficient on the eutectic instability, and the results are compared with those of Al--Cu alloys. Laser remelting experiments are performed and the transition growth velocity from eutectic to α-Al dendrite is examined. Compared with Al--Cu alloys, the eutectic instability takes place at a velocity more than one order of magnitude smaller. The theoretical calculation by the Trivedi--Magnin--Kurz (TMK) model also predicts that the eutectic will become instable at smaller growth velocity for Al--Sm alloy than Al--Cu alloy, which is ascribed to the low diffusion coefficient.
  • Article Text

  • [1] Zener C 1949 J. Appl. Phys. 20 950.
    [2] Kurz W and Fisher D J 1998 Fundamentals of
    Solidification 4^{th edn (Switzerland: Trans. Tech. Pub. Ltd.)
    [3] Trivedi R and Kurz W 1994 Acta Metall. Mater.
    42 15
    [4] Aziz M J 1982 J. Appl. Phys. 53 1158
    [5] Aziz M J 1994 Acta Metall. Mater. 42 527
    [6] Siegel J, Solis J, Afonso C N and Garc\'{\ia C 1996
    J. Appl. Phys. 80 6677
    [7] Inoue A, Ohtera K, Zhang T and Masunoto T 1988 Jpn.
    J. Appl. Phys. 27 L1583
    [8] Inoue A, Ohtera K and Masunoto T 1988 Jpn. J. Appl.
    Phys. 27 L736
    [9] Inoue A 1998 Prog. Mater. Sci. 43 365.
    [10] Wang N and Triedi R 2008 Metall. Mater. Trans. A
    (submitted)
    [11] Ejima T, Yamamura T, Uchida N, Matsuzaki Y and Nikaido M
    1980 J. Jpn. Inst. Met. 44 316.
    [12] Perepezko J H, Hebert R J and Wilde G 2004 Mater.
    Sci. Eng. A 375--377 171
    [13] Massacki T B 1986 Binary Alloy Phase Diagrams
    (Materials Park, OH: ASM) p 166
    [14] Trivedi R, David S A, Eshelman M A, Vitek J M, Babu S S,
    Hong T and DebRoy T 2003 J. Appl. Phys. 93 4885
    [15] Gremaud M, Carrard M and Kurz W 1990 Acta Metall.
    Mater. 38 2587
    [16] Zimmermann M, Karma A and Carrard M 1990 Phys. Rev.
    B 42 833
    [17] Zimmermann M, Carrard M and Kurz W 1989 Acta Metall.
    Mater. 37 3305
  • Related Articles

    [1]DING Ding, XIA Lei, YU Zhong-Hua, DONG Yuan-Da. Amorphization Induced High Magneto-Caloric Effect of Gd55Al20Ni25 Ternary Alloy [J]. Chin. Phys. Lett., 2008, 25(9): 3414-3417.
    [2]XIA Ai-Lin, FANG Yi-Kun, GUO Zhao-Hui, LI Wei, HAN Bao-Shan. Effect of Sm Volatilization on Magnetic Microstructures of Sintered Sm(Co,Fe,Cu,Zr)z Magnets at High Temperatures [J]. Chin. Phys. Lett., 2006, 23(5): 1289-1292.
    [3]HU Jian-Bo, YU Yu-Ying, TAN Hua, DAI Cheng-Da. Effect of Anneal on the Release Behaviour of LY12-Al Alloy [J]. Chin. Phys. Lett., 2006, 23(5): 1265-1268.
    [4]RUAN Ying, WANG Nan, CAO Chong-De, WEI Bing-Bo. Ternary Eutectic Growth in a Highly Undercooled Liquid Alloy [J]. Chin. Phys. Lett., 2004, 21(8): 1590-1592.
    [5]LIU Bing, CHEN Da-Rong, CHEN Zheng, WANG Yong-Xin, LI Xiao-Ling. Effect of Electric Field on Conductivity and Vickers Hardness of an Al-Li Alloy [J]. Chin. Phys. Lett., 2003, 20(11): 2067-2069.
    [6]ZHANG Lian-Shun, ZHANG Chun-Ping, WANG Xin-Yu, QI Sheng-Wen, XU Tang, TIAN Jiang-Guo, ZHANG Guang-Yin. Influence of Boundary Condition and Diffusion Coefficient on the Accuracy of Diffusion Theory in Steady-State Spatially Resolved Diffuse Reflectance of Biological Tissues [J]. Chin. Phys. Lett., 2002, 19(12): 1874-1876.
    [7]ZHOU Zheng-Cun, CHENG He-Fa, GONG Chen-Li, WEI Jian-Ning, HAN Fu-Sheng. Zener Relaxation Peak in an Fe-Cr-Al Alloy [J]. Chin. Phys. Lett., 2002, 19(11): 1660-1662.
    [8]S. Mahmood, Q. Haque, H. Saleem. Low Frequency Electromagnetic Instability in UnmagnetizedInhomogeneous Dusty Plasmas [J]. Chin. Phys. Lett., 2001, 18(3): 402-404.
    [9]WANG De-yu, M. Raadu, N. Brenning. Modulation Instability of Low Frequency Whistler Waves [J]. Chin. Phys. Lett., 1997, 14(4): 287-290.
    [10]LI Xiangyang, CHENG Huansheng, HE Wenquan, YANG Fujia. Diffusion of Silver in Nanometer Ni-B Amorphous Alloy [J]. Chin. Phys. Lett., 1994, 11(9): 577-580.

Catalog

    Article views (1) PDF downloads (707) Cited by()

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return