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Time-Dependent Quantum Dynamics of Dissociation for CH4 on an Ni(100) Surface

  • 1Laboratory for High Intensity Optics, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800 2Department of Physics, Shandong Normal University, Jinan 250014

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  • Published Date: March 31, 2004
    Abstract
  • The semirigid vibrating rotor target (SVRT) model proposed by Zhang [J. Chem. Phys. 111 (1999) 3929] is applied to study the dynamics of dissociative adsorption for CH4 on a flat and static Ni(100) surface. The molecule CH4 is treated as a semirigid vibrating rotor CH3-H, and the London-Eyring-Polanyi-Sato potential energy surface is utilized. The numerical calculation for the reaction system is carried out by using the time-dependent wave packet approach, and the propagation of wave packets is obtained by the split-operator method. The results demonstrate many important properties of the CH4 molecule dissociation process on the metal Ni. The dissociation probability is a strongly increasing function of the incident kinetic energy, and is enhanced significantly when the molecule CH4 is excited, which denotes the clear vibration-excitation effect, as observed in the molecular beam studies of Holmblad et al. [J. Chem. Phys. 102 (1995) 8255] The isotopic effect is also studied for molecules CH4 and CD4 at the ground rovibrational states.
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    1. Peng, W., Wang, Y., Zhao, Y. et al. Three-dimensional matter wave soliton transformation between different optical lattices in a cold Rydberg atomic system. Scientific Reports, 2025, 15(1): 1998. DOI:10.1038/s41598-025-86379-z
    2. He, X., Zhang, M., Li, P. et al. Effects of fractional diffraction on nonlinear PT phase transitions and stability of dark solitons and vortices. Optics Express, 2025, 33(5): 9369-9382. DOI:10.1364/OE.552001
    3. Fan, Z., Liu, W., Wang, L. et al. Vortex solitons in quasi-phase-matched photonic crystals with competing quadratic and cubic nonlinearity. Physical Review E, 2025, 111(3): 034208. DOI:10.1103/PhysRevE.111.034208
    4. Wu, D., Li, J., Gao, X. et al. Multicore vortex solitons in cubic–quintic nonlinear media with a Bessel lattice potential. Chaos, Solitons and Fractals, 2025. DOI:10.1016/j.chaos.2025.116057
    5. Peng, W., Wang, L., Xiao, L. et al. Vortex solitons in a Rydberg-dressed triangular optical lattice. Physics Letters, Section A: General, Atomic and Solid State Physics, 2025. DOI:10.1016/j.physleta.2025.130249
    6. Cheng, G., Liu, Z., Gao, Y. et al. Solitons in one-dimensional non-Hermitian moiré photonic lattice. Optics and Laser Technology, 2025. DOI:10.1016/j.optlastec.2024.111892
    7. Chen, S., Wang, L., Fan, Z. et al. Vortex light bullets in rotating Quasi-Phase-Matched photonic crystals with quadratic and cubic nonlinearity. Chaos, Solitons and Fractals, 2025. DOI:10.1016/j.chaos.2024.115777
    8. Fan, Z., Shi, Y., Wang, H. et al. Vortex clusters and their active control in a cold Rydberg atomic system with PT-symmetric Bessel potential. Chinese Physics B, 2024, 33(12): 120306. DOI:10.1088/1674-1056/ad8073
    9. Ma, Z., Han, H., Tian, L. Multiple solitons, multiple lump solutions, and lump wave with solitons for a novel (2+1)-dimensional nonlinear partial differential equation. Physica Scripta, 2024, 99(11): 115238. DOI:10.1088/1402-4896/ad831b
    10. He, J.-R., Jiao, Y., Zhou, B. et al. Vortex light bullets in rotating Quasi-Phase-Matched photonic crystals. Chaos, Solitons and Fractals, 2024. DOI:10.1016/j.chaos.2024.115514
    11. Felix-Rendon, U., Iakushev, D., Bilal, M.M. et al. Soliton dynamics in partially PT-symmetric two-dimensional Bessel lattices. Physica Scripta, 2024, 99(10): 105567. DOI:10.1088/1402-4896/ad7adc
    12. Zhao, Y., Huang, Q., Gong, T. et al. Three-dimensional solitons supported by the spin–orbit coupling and Rydberg–Rydberg interactions in PT-symmetric potentials. Chaos, Solitons and Fractals, 2024. DOI:10.1016/j.chaos.2024.115329
    13. Wang, Y., Cui, J., Zhang, H. et al. Rydberg-Induced Topological Solitons in Three-Dimensional Rotation Spin-Orbit-Coupled Bose-Einstein Condensates. Chinese Physics Letters, 2024, 41(9): 090302. DOI:10.1088/0256-307X/41/9/090302
    14. Xu, S., Li, J., Hou, Y. et al. Vortex light bullets in Rydberg atoms trapped in twisted PT -symmetric waveguide arrays. Physical Review A, 2024, 110(2): 023508. DOI:10.1103/PhysRevA.110.023508
    15. Laskar, R., Hossain, M.M., Saha, J.K. Investigating transfer of coherence, direction of light propagation and Rydberg blockade in a four-level Ξ-type system under linear and nonlinear interaction regimes. Optik, 2024. DOI:10.1016/j.ijleo.2024.171831
    16. Chen, S., Zhu, M., Peng, J. et al. Soliton transformation in a cold Rydberg atomic system. Results in Physics, 2024. DOI:10.1016/j.rinp.2024.107744
    17. Yang, A., Zhou, J., Liang, X. et al. Two-dimensional quantum droplets in binary quadrupolar condensates. New Journal of Physics, 2024, 26(5): 053037. DOI:10.1088/1367-2630/ad49c4
    18. Zhang, L.-J., Chen, A.-H., Wang, M.-Y. Elastic and resonant interactions of a lump and two parallel line solitary waves for the (4+1)-dimensional Fokas equation. Nonlinear Dynamics, 2024, 112(6): 4761-4773. DOI:10.1007/s11071-023-09269-x
    19. Wei, M., Chen, X. Traveling wave solutions for a Gardner equation with distributed delay under KS perturbation. Nonlinear Dynamics, 2024. DOI:10.1007/s11071-024-10627-6
    20. Zhao, N., Chen, Y., Cheng, L. et al. Data-driven soliton solutions and parameter identification of the nonlocal nonlinear Schrödinger equation using the physics-informed neural network algorithm with parameter regularization. Nonlinear Dynamics, 2024. DOI:10.1007/s11071-024-10562-6
    21. Xu, S.-L., Zhu, M., Peng, J.-X. et al. Light bullets in a nonlocal Rydberg medium with PT-symmetric moiré optical lattices. Chaos, Solitons and Fractals, 2023. DOI:10.1016/j.chaos.2023.114198
    22. Zhao, Y., Hu, H.-J., Zhou, Q.-Q. et al. Three-dimensional solitons in Rydberg-dressed cold atomic gases with spin–orbit coupling. Scientific Reports, 2023, 13(1): 18079. DOI:10.1038/s41598-023-44745-9
    23. Liu, B., Cai, X., Qin, X. et al. Ring-shaped quantum droplets with hidden vorticity in a radially periodic potential. Physical Review E, 2023, 108(4): 044210. DOI:10.1103/PhysRevE.108.044210
    24. Li, Z.-Y., Li, J.-H., Zhao, Y. et al. Robust light bullets in Rydberg gases with moiré lattice. Results in Physics, 2023. DOI:10.1016/j.rinp.2023.106990
    25. Zhou, J., Xie, S., Nie, C. et al. Optical properties of a Moiré-lattice photonic crystal fiber with controllable magic angle. Results in Physics, 2023. DOI:10.1016/j.rinp.2023.106659
    26. Xu, Y.-X., Zhao, Y., Huang, Q.-H. et al. Rydberg-dressed solitons in Bose-Einstein condensates with parity-time symmetry. Results in Physics, 2023. DOI:10.1016/j.rinp.2023.106534
    27. Liao, Q.-Y., Hu, H.-J., Chen, M.-W. et al. Two-dimensional spatial optical solitons in Rydberg cold atomic system under the action of optical lattice | [光晶格作用下里德伯冷原子系统中的二维空间光孤子]. Wuli Xuebao/Acta Physica Sinica, 2023, 72(10): 104202. DOI:10.7498/aps.72.20230096

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