Energy Level for a Type of Three-Particle Hamiltonian with Kinetic Couplings

  • For a triatomic molecule described by the Harniltonian with kinetic energy couplings, H = P21/(2m) +P22/(2m) + P23/(2M) + kP1P2 + KP1P3 + KP2P3 + V1(X2–X1 ) + V2x3 - ( X1+ X2) / 2 , its energy level formula is derived. The cases are consider when the potentials Vi (i = 1,2) are harmonic oscillator, or Morse potential, separately. Squeezing mechanism involved in the approach for solving this dynamic problem is revealed.
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