Breaking through the Optimization Limits of Power Factor via Pressure-Decoupled Seebeck Coefficient and Electrical Conductivity
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Dianzhen Wang,
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Muhammad Faizan,
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Jinming Zhu,
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Wanting Quan,
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Yanli Chen,
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Qiang Zhou,
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Kuo Bao,
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Yan Li,
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Qiang Tao,
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Lijun Zhang,
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Tian Cui,
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Pinwen Zhu
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Abstract
In thermoelectricity, the inherent coupling between electrical conductivity and Seebeck coefficient represents a fundamental challenge in thermoelectric materials development. Herein, we present a unique pressure-tuning strategy using compressible layered 2H-MoTe2, achieving an effective decoupling between the electrical conductivity and Seebeck coefficient. The applied pressure simultaneously induces two complementary effects: (1) bandgap reduction that moderately enhances carrier concentration to improve the electrical conductivity, and (2) band convergence that dramatically increases density-of-states effective mass to boost the Seebeck coefficient. This dual mechanism yields an extraordinary 18.5-fold enhancement in the average power factor. Firstprinciples calculations and Boltzmann transport modeling precisely reproduce the experimental observations, validating this pressure-induced decoupling mechanism. The pressure-tuning mechanism provides a feasible and effective strategy for breaking through the optimization limits of power factor, facilitating to design high-performance thermoelectric materials.
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Cite this article:
Dianzhen Wang, Muhammad Faizan, Jinming Zhu, Wanting Quan, Yanli Chen, Qiang Zhou, Kuo Bao, Yan Li, Qiang Tao, Lijun Zhang, Tian Cui, Pinwen Zhu. Breaking through the Optimization Limits of Power Factor via Pressure-Decoupled Seebeck Coefficient and Electrical Conductivity[J]. Chin. Phys. Lett.. DOI: 10.1088/0256-307X/42/6/066401
Dianzhen Wang, Muhammad Faizan, Jinming Zhu, Wanting Quan, Yanli Chen, Qiang Zhou, Kuo Bao, Yan Li, Qiang Tao, Lijun Zhang, Tian Cui, Pinwen Zhu. Breaking through the Optimization Limits of Power Factor via Pressure-Decoupled Seebeck Coefficient and Electrical Conductivity[J]. Chin. Phys. Lett.. DOI: 10.1088/0256-307X/42/6/066401
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Dianzhen Wang, Muhammad Faizan, Jinming Zhu, Wanting Quan, Yanli Chen, Qiang Zhou, Kuo Bao, Yan Li, Qiang Tao, Lijun Zhang, Tian Cui, Pinwen Zhu. Breaking through the Optimization Limits of Power Factor via Pressure-Decoupled Seebeck Coefficient and Electrical Conductivity[J]. Chin. Phys. Lett.. DOI: 10.1088/0256-307X/42/6/066401
Dianzhen Wang, Muhammad Faizan, Jinming Zhu, Wanting Quan, Yanli Chen, Qiang Zhou, Kuo Bao, Yan Li, Qiang Tao, Lijun Zhang, Tian Cui, Pinwen Zhu. Breaking through the Optimization Limits of Power Factor via Pressure-Decoupled Seebeck Coefficient and Electrical Conductivity[J]. Chin. Phys. Lett.. DOI: 10.1088/0256-307X/42/6/066401
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