Robust superconducting stability of ternary hydride Im-3m (Y, Ca)H6 upon decompression
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Abstract
Ternary hydrides, with their superior chemical and structural flexibility over binary systems, open up new avenues for advancing high-performance superconductor research. The Y-Ca-H system is a promising candidate for high-temperature superconductors, as both Im-3m YH6 and Im-3m CaH6 exhibit similar structure and excellent superconducting properties, while Y and Ca atoms possess close atomic radii and electronegativities. Here, we report the successful synthesis of Im-3m (Y, Ca)H6 achieving a maximum superconducting transition temperature (Tc) approximately 224 K at 155 GPa through five independent hightemperature and high-pressure experiments. Remarkably, the Tc of Im-3m (Y, Ca)H6 remains highly stable (ΔTc ≤ 1 K) during decompression between 148 and 165 GPa, significantly outperforming binary Im-3m CaH6 and Im-3m YH6. The enhanced superconducting properties may stem from the cooperative chemical template effect of Y and Ca atoms near the s-d border, which significantly reinforces H lattice stability and thus maintains superior superconductivity. This study highlights the potential of multicomponent cooperative effects in designing hydride superconductors, offering new insights for achieving high-Tc hydrides at lower pressures in the future.
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Cite this article:
Kexin Zhang, Jianning Guo, Yulong Wang, Xinyue Wu, Xiaoli Huang, Tian Cui. Robust superconducting stability of ternary hydride
Im-3
m (Y, Ca)H
6 upon decompression[J].
Chin. Phys. Lett..
DOI: 10.1088/0256-307X/42/11/110704
Kexin Zhang, Jianning Guo, Yulong Wang, Xinyue Wu, Xiaoli Huang, Tian Cui. Robust superconducting stability of ternary hydride Im-3m (Y, Ca)H6 upon decompression[J]. Chin. Phys. Lett.. DOI: 10.1088/0256-307X/42/11/110704
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Kexin Zhang, Jianning Guo, Yulong Wang, Xinyue Wu, Xiaoli Huang, Tian Cui. Robust superconducting stability of ternary hydride Im-3m (Y, Ca)H6 upon decompression[J]. Chin. Phys. Lett.. DOI: 10.1088/0256-307X/42/11/110704
Kexin Zhang, Jianning Guo, Yulong Wang, Xinyue Wu, Xiaoli Huang, Tian Cui. Robust superconducting stability of ternary hydride Im-3m (Y, Ca)H6 upon decompression[J]. Chin. Phys. Lett.. DOI: 10.1088/0256-307X/42/11/110704
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