Ultrafast Carrier Dynamics and Terahertz Photoconductivity of Mixed-Cation and Lead Mixed-Halide Hybrid Perovskites
-
Abstract
Using time-dependent terahertz spectroscopy, we investigate the role of mixed-cation and mixed-halide on the ultrafast photoconductivity dynamics of two different methylammonium (MA) lead-iodide perovskite thin films. It is found that the dynamics of conductivity after photoexcitation reveals significant correlation on the microscopy crystalline features of the samples. Our results show that mixed-cation and lead mixed-halide affect the charge carrier dynamics of the lead-iodide perovskites. In the (5-AVA)(MA)PbICl/spiro thin film, we observe a much weaker saturation trend of the initial photoconductivity with high excitation fluence, which is attributed to the combined effect of sequential charge carrier generation, transfer, cooling and polaron formation. -
-
References
[1] Lee M M, Teuscher J, Miyasaka T, Murakami T N and Snaith H J 2012 Science 338 643 doi: 10.1126/science.1228604[2] Manser J S, Christians J A and Kamat P V 2016 Chem. Rev. 116 12956 doi: 10.1021/acs.chemrev.6b00136[3] Liu M, Johnston M B and Snaith H J 2013 Nature 501 395 doi: 10.1038/nature12509[4] Guo Z, Manser J S, Wan Y, Kamat P V and Huang L 2015 Nat. Commun. 6 7471 doi: 10.1038/ncomms8471[5] Xing G, Mathews N, Sun S, Lim S S, Lam Y M, Grätzel M, Mhaisalkar S and Sum T C 2013 Science 342 344 doi: 10.1126/science.1243167[6] Etgar L, Gao P, Xue Z, Peng Q, Chandiran A K, Liu B, Nazeeruddin M K and Grätzel M 2012 J. Am. Chem. Soc. 134 17396 doi: 10.1021/ja307789s[7] Saliba M, Matsui T, Seo J, Domanski K, Correa-Baena J P, Nazeeruddin M K, Zakeeruddin S M, Tress W, Abate A, Hagfeldt A, and Grätzel M 2016 Energy Environ. Sci. 9 1989 doi: 10.1039/C5EE03874J[8] Jeon N J, Na H, Jung E H, Yang T Y, Lee Y G, Kim G, Shin H, Seok S, Lee J and Seo J 2018 Nat. Energy 3 682 doi: 10.1038/s41560-018-0200-6[9] Ren Y, Ding X, Wu Y, Ren Y K, Ding X H, Wu Y H, Zhu J, Hayat T, Alsaedi A, Xu Y, Li Z, Yang S and Dai S Y 2017 J. Mater. Chem. A 5 20327 doi: 10.1039/C7TA06334B[10] Ren Y, Shi X, Ding X, Zhu J, Hayat T, Alsaedi A, Li Z, Xu X, Yang S and Dai S Y 2018 Inorg. Chem. Front. 5 348 doi: 10.1039/C7QI00685C[11] Ren Y, Duan B, Xu Y, Huang Y, Li Z, Hu L, Hu L, Hayat T, Wang X, Zhu J and Dai S 2017 Sci. Chin. Mater. 60 392 doi: 10.1007/s40843-017-9027-1[12] Lin K, Xing J, Quan L, de Arquer F P G, Gong X, Lu J, Xie L, Zhao W, Zhang D, Yan C, Li W, Liu X, Lu Y, Kirman J, Sargent E H, Xiong Q and Wei Z 2018 Nature 562 245 doi: 10.1038/s41586-018-0575-3[13] Luo J, Wang X, Li S, Liu J, Guo Y, Niu G, Yao L, Fu Y, Gao L, Dong Q, Zhao C, Leng M, Ma F, Liang W, Wang L, Jin S, Han J, Zhang L, Etheridge J, Wang J, Yan Y, Sargent E H and Tang J 2018 Nature 563 541 doi: 10.1038/s41586-018-0691-0[14] Ivanovska T, Dionigi C, Mosconi E, De Angelis F, Liscio F, Morandi V and Ruani G 2017 J. Phys. Chem. Lett. 8 3081 doi: 10.1021/acs.jpclett.7b01156[15] Zhu X Y and Podzorov V 2015 J. Phys. Chem. Lett. 6 4758 doi: 10.1021/acs.jpclett.5b02462[16] Motta C and Sanvito S 2018 J. Phys. Chem. C 122 1361 doi: 10.1021/acs.jpcc.7b10163[17] McMeekin D P, Sadoughi G, Rehman W, Eperon G E, Saliba M, Hörantner M T, Haghighirad A, Sakai N, Korte L, Rech B, Johnston M B, Herz L M and Snaith H J 2016 Science 351 151 doi: 10.1126/science.aad5845[18] Jeon N J, Noh J H, Yang W S, Kim Y C, Ryu S, Seo J and Seok S I 2015 Nature 517 476 doi: 10.1038/nature14133[19] Mei A, Li X, Liu L, Ku Z, Liu T, Rong Y, Xu M, Hu M, Chen J, Yang Y, Grätzel M and Han H 2014 Science 345 295 doi: 10.1126/science.1254763[20] Pei Y, Zou X, Guan Y and Teng G 2016 Int. J. Photoenergy 2016 2953592 doi: 10.1155/2016/2953592[21] Stranks S D, Eperon G E, Graneini G, Menelaou C, Alcocer M J P, Leijtens T, Herz L M, Petrozza A and Snaith H J 2013 Science 342 341 doi: 10.1126/science.1243982[22] Karakus M, Jensen S A, D'Angelo F, Turchinovich D, Bonn M and Canovas E 2015 J. Phys. Chem. Lett. 6 4991 doi: 10.1021/acs.jpclett.5b02485[23] Ulbricht R, Hendry E, Shan J, Heinz T F and Bonn M 2011 Rev. Mod. Phys. 83 543 doi: 10.1103/RevModPhys.83.543[24] Noh J H, Im S H, Heo J H, Mandal T N and Seok S I 2013 Nano Lett. 13 1764 doi: 10.1021/nl400349b[25] Papavassiliou G C, Pagona G, Karousis N, Mousdis G A, Koutselas I and Vassilakopoulou A 2012 J. Mater. Chem. 22 8271 doi: 10.1039/c2jm15783g[26] Qiu J, Qiu Y, Yan K, Zhong M, Mu C, Yan H and Yang S 2013 Nanoscale 5 3245 doi: 10.1039/c3nr00218g[27] Mosconi E, Amat A, Nazeeruddin M K, Grätzel M and De Angelis F 2013 J. Phys. Chem. C 117 13902 doi: 10.1021/jp4048659[28] Guo X, McCleese C, Kolodziej C, Samia A C, Zhao Y and Burda C 2016 Dalton Trans. 45 3806 doi: 10.1039/C5DT04420K[29] Schmuttenmaer C A 2004 Chem. Rev. 104 1759 doi: 10.1021/cr020685g[30] Joyce H J, Bol, J L, Davies C L, Baig S A and Johnston M B 2016 Semicond. Sci. Technol. 31 103003 doi: 10.1088/0268-1242/31/10/103003[31] Ponseca Jr C S, Savenije T J, Abdellah M, Zheng K, Yartsev A, Pascher T, Harlang T, Chabera P, Pullerits T, Stepanov A, Wolf J and Sundstrom V 2014 J. Am. Chem. Soc. 136 5189 doi: 10.1021/ja412583t[32] Marchioro A, Teuscher J, Friedrich D, Kunst M, Krol R, Moehl T, Grätzel M and Moser J 2014 Nat. Photon. 8 250 doi: 10.1038/nphoton.2013.374[33] Yan H J, Ku Z L, Hu X F, Zhao W Y, Zhong M J, Zhu Q B, Lin X, Jin Z M and Ma G H 2018 Chin. Phys. Lett. 35 028401 doi: 10.1088/0256-307X/35/2/028401[34] Zhang Z, Lin T, Xing X, Lin X, Meng X, Cheng Z, Jin Z and Ma G 2017 Appl. Phys. Lett. 110 111108 doi: 10.1063/1.4978647[35] Jensen S A, Mics Z, Ivanov I, Varol H S, Turchinovich D, Koppens. H L F, Bonn M and Tielrooij K J 2014 Nano Lett. 14 5839 doi: 10.1021/nl502740g[36] Bretschneider S A, Ivanov I, Wang H I, Miyata K, Zhu X and Bonn M 2018 Adv. Mater. 30 1707312 doi: 10.1002/adma.201707312[37] Ponseca Jr C S, Tian Y, Sundström V and Scheblykin I G 2016 Nanotechnology 27 082001 doi: 10.1088/0957-4484/27/8/082001[38] Wehrenfennig C, Eperon G E, Johnston M B, Snaith H J and Herz L M 2014 Adv. Mater. 26 1584 doi: 10.1002/adma.201305172[39] Johnston M B and Herz L M 2016 Acc. Chem. Res. 49 146 doi: 10.1021/acs.accounts.5b00411[40] Yan H, An B, Fan Z, Zhu X, Lin X, Jin Z and Ma G 2016 Appl. Phys. A 122 414 doi: 10.1007/s00339-016-9957-2[41] Yang Y, Yan Y, Yang M, Choi S, Zhu K, Luther J M and Beard M C 2015 Nat. Commun. 6 7961 doi: 10.1038/ncomms8961[42] Ghosh T, Aharon S, Etgar L and Ruhman S 2017 J. Am. Chem. Soc. 139 18262 doi: 10.1021/jacs.7b09508[43] Jha A, Duan H G, Tiwari V, Nayak P K, Snaith H J, Thorwart M and Miller R D 2018 ACS Photon. 5 852 doi: 10.1021/acsphotonics.7b01025[44] Frost J M 2017 Phys. Rev. B 96 195202 doi: 10.1103/PhysRevB.96.195202[45] Sendner M, Nayak P K, Egger D A, Beck S, Müller C, Epding B, Kowalsky W, Kronik L, Snaith H J, Pucci A and Lovrinčić R 2016 Mater. Horizons 3 613 doi: 10.1039/C6MH00275G[46] Glover I I I R E and Tinkham M 1957 Phys. Rev. 108 243 doi: 10.1103/PhysRev.108.243[47] Jin Z, Gehrig D, Dyer-Smith C, Heilweil E J, Laquai F, Bonn M and Turchinovich D 2014 J. Phys. Chem. Lett. 5 3662 doi: 10.1021/jz501890n -
Related Articles
[1] LUO Xiao-Guang, HE Ju-Long. B–C–N Compounds with Mixed Hybridization of sp2-Like and sp3-Like Bonds [J]. Chin. Phys. Lett., 2012, 29(3): 036104. doi: 10.1088/0256-307X/29/3/036104 [2] MA Zhi-Zuo, ZHANG Chen-Hui, LUO Jian-Bin, LU Xin-Chun, WEN Shi-Zhu. Superlubricity of a Mixed Aqueous Solution [J]. Chin. Phys. Lett., 2011, 28(5): 056201. doi: 10.1088/0256-307X/28/5/056201 [3] YU Zong-Wen. Optimal Broadcasting of Mixed Equatorial Qubits [J]. Chin. Phys. Lett., 2009, 26(8): 080304. doi: 10.1088/0256-307X/26/8/080304 [4] LIN Qing, LI Jian, GUO Guang-Can. Superadditivity with Mixed States Ensemble [J]. Chin. Phys. Lett., 2005, 22(5): 1057-1060. [5] ZHANG Li-Yan, YANG Jian-Hu, HU Li-Li, JIANG Zhong-Hong. High Efficiency Infrared to Visible Upconversion in Er3+/Yb3+-Doped Lead Halide Tellurite Glass [J]. Chin. Phys. Lett., 2003, 20(8): 1344-1346. [6] TONG Dian-Min, CHEN Jing-Ling, DU Jiang-Feng. Geometric Phase for Mixed States [J]. Chin. Phys. Lett., 2003, 20(6): 793-795. [7] K. Afif, A. Benyoussef, M. Hamedoun. Monte Carlo Simulations of Mixed Highly Frustrated Systems [J]. Chin. Phys. Lett., 2002, 19(8): 1187-1190. [8] QUAN Hong-Jun, WANG Bing-Hong, HUI Pak-Ming, LUO Xiao-Shu. Cooperation in the Mixed Population Minority Game with Imitation [J]. Chin. Phys. Lett., 2001, 18(9): 1156-1158. [9] WEI Jian-hua, LIU De-sheng, XIE Shi-jie, MEI Liang-mo. Quantum Charge Transfer in Quasi-One-Dimensional Mixed Halide Compounds [J]. Chin. Phys. Lett., 1998, 15(10): 737-738. [10] ZHENG Hang. A NEW MODEL FOR THE MIXED VALENCE COMPOUNDS [J]. Chin. Phys. Lett., 1987, 4(1): 33-36.
DownLoad: