Superconductivity Tuned by the Iron Vacancy Order in KxFe2?ySe2

  • Combining in-depth neutron diffraction and systematic bulk studies, we discover that the √5×√5 Fe vacancy order, with its associated block antiferromagnetic order, is the ground state with varying occupancy ratios of the iron 16#em/em# and vacancy 4d sites across the phase-diagram of KxFe2?ySe2. The orthorhombic order, with one of the four Fe sites vacant, appears only at intermediate temperatures as a competing phase. The material experiences an insulator to metal crossover when the √5×√5 order is highly developed. Superconductivity occurs in such a metallic phase.
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