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Correlation between Carrier Concentration and Superconductivity in the 123-phase System
HE Zhenhui, XIA Jiansheng, WANG Shunxi, CAO Liezhao, CHEN Zuyao, ZHANG Han, FANG Minghu, XU Zhu’an, ZHANG Qirui
Chin. Phys. Lett. 1991, 8 (5):
259-262
.
Besides the structure and oxygen content, the resistance-temperature relationship, Hall carrier concentration (nH) and midpoint temperature of superconducting transition (Tc) were measured for more than six 123-phase systems with elemental substitution. No correlation is found between the oxygen content and Tc, nor is between the orthorhombic structure and Tc. Instead, an unmonotonic relationship is jound between nH and Tc. The optimum nH for the highest Tc is about 3.8 x1021cm-3. All this draws a conclusion that nH is a parameter to describe the high Tc superconductivity.
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Crystallographic and Magnetic Properties of R2 Fe17Cx with R=Y, Pr, Nd, Sm, Gd, Dy, and Er
LIN Qin, SUN Yunxi, LAN Jian, LU Shizhong, JIANG Hongwei
Chin. Phys. Lett. 1991, 8 (5):
267-270
.
A series of R2 Fe17Cx compounds (R=Y, Pr, Nd, Sm, Gd, Dy, and Er; x=0, 0.5 and 1.0) were synthesized. X-ray diffraction analyses showed that the crystal structure is rhombohedral Th2Zn17 type for R=Pr, Nd, Sm, and Gd. For R=Y, Dy and Er, a structure transformation from hexagonal Th2Ni17 type (x=0.5) to rhombohedral Th2Zn17 type (x=1.0) was observed. The introduction of C into R2Fe17 leads to an expansion of the lattice. It strongly enhances Curie temperature. C atoms occupy interstitially the nearest neighbour sites to the R atoms in the lattice. The anisotropy of R sublattice was strengthened. A uniaxial anisotropy was observed in Sm2Fe17C0.5 at room temperature.
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15 articles
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