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Growth and Properties of Tungsten Bronze-Type Second Harmonic Generation Crystal LiBa2Nb5O15
CHENG Ruiping, DONG Shengming, SONG Yongyuan, ZHANG Peilin*, ZHONG Weilie*
Chin. Phys. Lett. 1993, 10 (1):
33-36
.
Striation-free LiBa2Nb5O15 (LBN) single crystal of good optical quality has been grown by Czochralski method. The crystal growth and dielectric, structural, spectral properties of LBN were measured. Experimental results show that LBN single crystal belongs to tetragonal tungsten bronze structure at room temperature. Experiments carried out with LBN powder samples have shown that this crystal has good second harmonic generation effect. At room temperature, the dielectric constant 33 is about 87 and Curie temperature Tc, is about 586°C. A very ideal uniaxial conoscope image can be observed in LBN single crystal under polarizing microscope. In the range of 600 to 2600nm, the transmission of single crystal is about 75%.
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New 1222-Type Thallium-Indium Layered Cuprates (Tl, In)Sr2(Nd, Ce)2Cu2Oz and Their Superconductivity
CHEN Zuyao*, TANG Yongqiu**, Z. Z. Sheng, Y . F. Li, D. O. Pederson,
Chin. Phys. Lett. 1993, 10 (1):
49-52
.
A new series of 1222-type thallium-indium layered cuprate compounds (Tl, In)Sr2(Nd, Ce)2Cu2Oz have been successfully synthesized in the pure or nearly pure form and identified by powder x-ray diffraction analyses. The structure of the compounds is directly related to that of Nb-1222 NbSr2(Nd, Ce)2Cu2Oz, with a tetragonal body-center lattice. The lattice parameters are a=3.85Å, c=29.56Å for (Tl0.7ln0.3)Srz(Nd0.5Ce0.5)2Cu2Oz, and a=3.85Å, c=29.28Å for lnSr2(Nd0.75Ce0.25)2Cu2Oz. Resistance measurements showed that (T11-xInx)Sr2(Nd0.75Ce0.25)2Cu2Oz(x ≤ 0.8) are superconducting with Tc(onset)=30-40K .
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17 articles
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