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Solid C60: Pressure Induced Phase Transitions
WANG Jifang, WANG Lijun, CHEN Liangchen, CHEN Hong, WANG Ruju, ZHANG Zhiting, CHE Rongzheng, ZHOU Lei
Chin. Phys. Lett. 1993, 10 (3):
159-162
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Based on in situ high pressure x-ray diffraction with diamond anvil cell by using synchrotron radiation and pressure-quench x-ray measurement, phase transition of C60 under high pressured is studied. The maximum pressure used is 30GPa in quasi-hydrostatic case but 44GPa in nonhydrostatic case. At ambient pressure, C60 crystal is a fcc phase with lattice parameter a=14.2086Å. It transforms from fcc to a lower symmetry phase at pressure of 13.7GPa, and then transforms to an amorphous state under pressure up to 25-30 GPa. This amorphous state is metastable at normal condition. Finally, the experimental results are discussed.
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Plasmon Excitation in 2D and 3D C60 Studied by Photoemission
XUN Kun, DENG Junzhuo, YAO Jun, LIU Fengqin, TAO Xiaoping, LÜ, Si hua, WANG Zuquan, WU Sicheng,
Chin. Phys. Lett. 1993, 10 (3):
167-170
.
For near monolayer (ML) C60 condensed on Sn substrate, x-ray photoemission studies of Cls level reveal a feature centered about 22eV below the main peak. Analyses show that the feature is caused by the plasmon loss of the two dimensional C60 film. Bulk plasmon loss peak(~ 28 eV blow the main peak), which has been observed on thick C60 films, was not observed on the C60 films with coverage θ < 2 ML. It indicates that the 28eV energy loss feature is due to a bulk plasmon associated with the solid C60 but not a single C60 molecule.
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Magnetostriction of RFe11Ti and RFe10Cr2
LI Jingyuan, LI Qing an, YANG Fuming, LI Ruqi, FAN Xiaoli, ZMAO Xuegen, JIA Kechang
Chin. Phys. Lett. 1993, 10 (3):
179-182
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The magnetostriction of polycrystal RFe11Ti (R=Nd, Sm, Gd, Tb, Dy, Ho, Er and Y) and RFe10Cr2(R=Tb and Dy) compounds with ThMn12-typestructure have been investigated at 77K and room temperature in magnetic fields up to 20kOe. The values ofmagnetastriction λt = λ|| - λ⊥ in H=20kOe at 300K are 180 x10-6 for TbFe11Ti and 106x10-6 for Tb10Cr2. The magnetostrictions for compounds with R=Nd, Sm, Dy, Ho and Er are very small. The signs of λt for all these compounds are in agreement with that predicted by the singleion crystal field theory. All studied samples show a volume magnetostriction feature. Their forced magnetostrictions Δω/ΔH have a value which is close to that of YFe11Ti, 27 x 10-10/Oe. It reveals that the Fe sublattice is responsible for the volumc magnetostriction.
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17 articles
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