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Temperature Characteristics of Raman Spectra in Nanometer Material Titanium Dioxide
WU Xijun, ZHANG Ming-sheng, YIN Zhen, JI Xiaoli, CHEN Qiang
Chin. Phys. Lett. 1994, 11 (11):
685-688
.
Raman spectra of the nanophase titanium dioxide were examined at various annealing temperatures. The temperature dependences of the Raman modes at 702, 612, 422, 230 -250, and 152cm-1 are discussed. The 702 cm-1 A2g mode belongs to first-order phonon connected to a critical nature of the selection rules with respect to the grain size. Lower anatase-rutile transition temperature 700°C is closely related to smaller grain size. The Eg mode at 422 cm-1 at room temperature shifts upward 24 cm-1 after successive annealing in air for one hour at 700°C, indicating the dependence of the lower mode frequency upon the larger oxygen deficiency.
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Photoemission Studies of K-Promoted Nitridation of InP (100)
Surface Using Synchrotron Radiation
ZHAO Texiu, JI Hong, LIANG Qi, WANG Xiaoping, XU Pengshou, LU Erdong, WU Jianxin, XU Zhenjia
Chin. Phys. Lett. 1994, 11 (11):
697-700
.
The effect of molecular nitrogen exposure on the surfaces of InP(100) modified by potassium overlayers is investigated by core-level and valence-band photoemission spectroscopy using Synchrotron radiation. In comparison with InP(110) surface, we found the promotion is much stronger for InP(100) surface due to the central role of surface defects in the promotion; furthermore, in contrast with K-promoted oxidation of InP(100) where the bonding is observed between indium and oxygen, indium atoms did not react directly with nitrogen atoms during the K-promoted nitridation of InP(100).
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High Temperature Limit of Weak Localization in Thin Silver Films
LI Guohong, WANG Min, CHEN Mingling, LIU Guoliang, LIU Sangtian,
WANG Shiguang, YAN Shousheng
Chin. Phys. Lett. 1994, 11 (11):
701-704
.
The behavior of magnetoresistance in thin silver films was investigated from 1.8 up to 104 K. Weak localization effect, manifested by negative magnetoresistance, remains until 88 K in magnetic fields below 2T. Experimental results indicate that weak localization theory for two-dimensional disordercd systems is applicable even when the phase relaxation length L is a few times longer than the elastic mean free path l, provided L is larger than the thickness of films. The obtained phase relaxation time τ obeys 1/T2.6 law.
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16 articles
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