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Factors Influencing Thermal Conductivity in Diamond Film
GU Chang-zhi, JIN Zeng-sun, WANG Chun-lei, LÜ, Xian-yi, ZOU Guang-tian, ZHANG Ji-fa*, FANG Rong-chun*
Chin. Phys. Lett. 1996, 13 (9):
700-702
.
Diamond films were synthesized on Si substrate by electron-assisted chemical vapor deposition method using gas mixtures of methane (or acetone) and hydrogen. Various crystal structures of diamond films were obtained by synthesis with various deposition conditions. The influences of various deposition conditions on thermal conductivity of diamond film were studied. The results show that large-grain (100)-oriented diamond films synthesized at lower concentration of methane and acetone have higher thermal conductivity, and thermal conductivity increases with the increasing in film thickness and the removal of the Sic layer on the back of the film, at last, annealing in ambience of hydrogen is advantageous to acquiring diamond film with high thermal conductivity.
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Formation of Carbon Nitride Films by Nitrogen Ion Bombardment on C60 Films
REN Zhong-min, DU Yuan-cheng, YING Zhi-feng, LI Fu-ming, LIN Jing, REN Yun-Zhu, ZONG Xiang-fu
Chin. Phys. Lett. 1996, 13 (9):
714-717
.
The synthesis of covalent carbon nitride films becomes an important subject in the materials research field. As a new synthetic method two low-energy (400 and 1000eV) nitrogen ion beams are used to bombard on C60 thin films individually. The bombarded films are used for Raman and x-ray photoelectron spectroscopy (XPS) measurements. The results of the analyses show that under the bombardment of 400eV nitrogen ion beam, the film still contains a large amount of undestructed C60 molecules. In the case of l000eV bombardment, only a little amount of C60 molecules is kept undestructed. The experimental results also show that the destructed carbon species will combine chemically with nitrogen ions to form stable covalent carbon nitride, confirmed by the Raman peaks of, e.g., 2240cm-1. The XPS Nls and Cls lines also indicate the formation of covalent carbon nitride in the bombarded films.
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22 articles
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