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Chemical Shifts of 23Na in NaCl Crystal Specimens Implanted with Xenon Ions
LIANG Jia-chang, , XU Zhou, LE Xiao-yun, ZHAO Wei-jiang, YU Fu-chun, LIU Zhi, CHEN Rong-ti, SUN Xian-ping, ZHENG Xi-zhi, DU Yo-ru, ZHAO Ming-xin, SHEN Lian-fang, GU Hong-en, LI Yi, SU Yi
Chin. Phys. Lett. 1999, 16 (8):
563-564
.
Na clusters containing 10 to less than 1000 metal sodium atoms and blisters containing xenon inclusions were formed in NaCl crystal specimens prepared by xenon ion implantation to single crystal NaCl with Auences more than or equal to 2 x 1016/cm2 at the energy of 36keV. Experiments indicated that on the condition of xenon ion Auences more than or equal to 1 x 1017/cm2 the xenon inside the inclusions formed in NaCl crystal specimens is in solid state and the solid state molecules NaXe are formed through the Combination of Xe with Na in Na clusters. The chemical shift of 23Na in solid state molecules NaXe relative to 23Na in single crystal NaCl was measured and is equal to -17ppm.
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Structure Effect of Squarylium Cyanine Dyes on Third-Order Optical Nonlinearities in Ground and Excited States
LIU Xu-chun, XU Gang, SI Jin-hai, YE Pei-xian, LIN Tong, PENG Bi-xian
Chin. Phys. Lett. 1999, 16 (8):
571-573
.
A series of squarylium cyanine dyes with different substituents were synthesized and the third-order optical nonlinearities of their ground and excited states were investigated by backward degenerate four-wave-mixing. For the ground state, the molecular hyperpolarizability γg increases with the red-shift of the absorption peak λabmax, of the squaraine with different substituents, whereas for the excited-state molecular hyperpolarizability γe, the nonlinear enhancement γe/γg decreases, which may indicate that in the excited state the electron accepting-donating ability of different substituents changes in the reverse order compared with the order in the ground state.
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Local Atomic Structure of Piperidyl Nd Dithiocarbamate
WU Zhong-hua, GUO Lin, JU Xin, HU Tian-dou, LI Qian-shu, ZHU He-sun,
Chin. Phys. Lett. 1999, 16 (8):
583-585
.
The atomic structure of a novel rare earth complex consisting of Nd and the sulfur-containing ligand pipdtc (C5H10NCS-2) has been studied with extended x-ray absorption fine structure (EXAFS} and x-ray diffraction techniques. The complex of formula Nd(pipdtc)4N(CH3)4 crystallizes in the monoclinic space group P21/n with the following lattice parameters, a = 22.685(2), b = 20.332(2), c = 17.1270(10)Å, β = 100.570(10)o, Z = 8. The calculated density is 1.47g/cm3. A new derivative method is used to remove the post-edge absorption background including the multielectron excitation effect. The EXAFS results demonstrate that there are about eight S and four O atoms around Nd with the Nd-S bond length of 2.916Å and the Nd-O bond length of 2.415Å, respectively. This implies that the powder of this complex is not stable and is easy to oxidize in air. The possible change of structure before and after oxidation is discussed.
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Effect of Carbon Content on Mechanoreduction of Copper Oxide
LIU Lin, YUAN Song-liu, DONG Yuan-da, CUI Kun
Chin. Phys. Lett. 1999, 16 (8):
591-593
.
The reduction of CuO with different amount of carbon (CuO:C=2:1, 2:1.5, and 2:2, in molar ratio) induced by ball milling is examined by x-ray diffraction and transmission electron microscopy. It is found that reduction process is closely related to the carbon content. CuO can be completely converted into Cu if an excessive C is used (i.e., C = 1.5 or 2.0mol). However, the reduction of CuO follows a two-step process, CuO→Cu→Cu2O, if the mixture only contains a nominal C content (i.e., C = 1 mol). A tentative model in terms of solid state reaction at the interfaces is proposed to explain the effect of carbon content on the mechanoreduction of CuO.
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Study of Blue Emission from Nano-SiC Powders During Rapid Thermal Annealing
LIU Yu-zhen, SHI Wan-quan, HUANG Yun-lan, LIU Shi-xiang, HAN Yi-qin, LU Zhong-qian, TAN Shou-hong, JIANG Dong-liang
Chin. Phys. Lett. 1999, 16 (8):
602-604
.
Nanometric SiC powder was prepared by chemical vapor deposition at 1100°C, and samples were subsequently treated by rapid thermal annealing at 600-1100°C. The intensities of the blue photoluminescence were then measured a t room temperature. The peak intensity at 2.56 eV (484 nm) rises with annealing temperature, reaching a value about 9.2 times as high at 800°C, then drops very quickly at 900°C. Based on the results of x-ray diffraction, infrared spectroscopy, x-ray photoelectron spectroscopy and transmission electron microscopy, we conclude that the amounts of the twofold coordinated Si on the surface of the nanometric SiC particles play an important role in the photoluminescence intensity.
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Abundances of the Neutron-Capture Elements in Metal-Poor Halo Star HD 126238
LI Ji, ZHANG Bo, WEI Guo-qiang, ZHANG Li-ping, PENG Qiu-he,
Chin. Phys. Lett. 1999, 16 (8):
619-621
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Using the new observations of several neutron-capture elements in metal-poor star HD 126238, combining a computer model and the method of least square, we accurately compute the component coefficients C1, C2, and C3. The results are C1 = 2.52, C2 = 0.26, C3 = 0.31. Then employing the values of the component coefficients, we determine the relative contributions of the r-process and the s-process to the abundances of neutron-capture elements in the HD 126238, and predict the abundances of all the neutron-capture elements in this metal-poor star. The predictions agree well with the observations.
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Cosmic Ray Composition in the “Knee”Region Deduced from the Lateral Distribution of Cerenkov Light Emitted in Extensive Air Showers
ZHA Min, CHUENG Tsang, DING Lin-kai, GAO Xiao-yu, GENG Qing-xi, LIU Chang-qin, NG Pun-Hon, YANG Hong-tao, ZHU Qing-qi
Chin. Phys. Lett. 1999, 16 (8):
622-624
.
We report the first result of measurements of the lateral distribution of Cerenkov light associated with cosmic ray extensive air showers with size between 105.0 and 106.6 observed in the Liangwang Mountain Observatory, 90 km east of Kunming City in China. The change trend towards heavy nucleus dominance of the primary cosmic ray composition in the “Knee”region is deduced with the aid of a Monte Carlo simulation.
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28 articles
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