|
Autoionizing Distribution of the Triply Excited Double Rydberg States in La Atom
SUN Wei, XIE Xiu-Ping, HUANG Wen, ZHONG Zhi-Ping, XU Cheng-Bin, XUE Ping, XU Xiang-Yuan,
Chin. Phys. Lett. 2000, 17 (6):
405-407
.
The autoionization distribution o f the triply excited double Rydberg states (TEDRS) 5d5/2NLnl (N ≤ 2 2 ; n≤ 50; L, l < 4) of La has been investigated by using five-laser resonance excitation in combination with a method of sequential ionization by a pulsed electric field and a constant electric field. The experimental results exhibit that the La atoms in TEDRS predominantly single-autoionize to the ionic Rydberg states located in a few Rydberg manifolds. Furthermore, a difference of autoionization mechanisms between TEDRS above and those below the double ionization threshold is found.
|
|
Structural Origin of the Formation of Odd-Numbered Carbon Clusters from Fullerene Derivatives
KONG Qing-Yu, ZHUANG Jun, ZHAO Li, WANG Jia-Yu, QIAN Shi-Xiong, LI Yu-Fen, LI Xu, ZHONG Chao-Fan, CAI Rui-Fang, YU Yong, HOU Hui-Qic
Chin. Phys. Lett. 2000, 17 (6):
419-422
.
We report the mass spectrometric investigation on fullerene derivatives C60CH2, C60RH , C60R2(R = C6H5 CO-) and C60On under the 308nm laser ablation. In the negative ion mass spectra of C60CH2, C60R2 and C60On odd-numbered clusters C-57,C-55, C-53, C-51 are observed clearly in addition to the even-numbered fullerene fragment ions, while for the monoadduct C60 RH,, odd-numbered species can not be detected. In the positive ion channel, the fragmentation patterns of the three derivatives are similar
|
|
Pump Intensity Dependence of Two-Beam Coupling in Doped Lithium Niobate Crystals
Nouel Y. Kamber, XU Jing-Jun, Sonia M. Mikha, SONG Feng, ZHANG Guo-Quan, ZHANG Xin-Zheng, LIU Si-Min, ZHANG Guang-Yin
Chin. Phys. Lett. 2000, 17 (6):
431-432
.
We demonstrated experimentally the dependence of two-beam coupling on the incident pump intensity in our samples of doped LiNbO3 crystals. Our results show that there is an optimum pump intensity for the signal beam amplification, which can be easily controlled by doping the LiNbO3 crystal with suitable concentrations of Fe and damage-resistant dopants such as Mg, In, and Zn.
|
|
Cluster Model for K(Ta0.56Nb0.44)O3 Solid Solution
PENG Yi-Ping, LI Hua, WANG Chun-Lei, ZHANG Lei, ZHANG Pei-Lin, ZHONG Wei-Lie
Chin. Phys. Lett. 2000, 17 (6):
438-440
.
Based on the results of total-energy calculations for embedded clusters using self-consistent-field Xα-scattered-wave method, we determined the tetragonal fine structure of K(Ta0.56Nb0.44)O3, i.e., the equilibrium configuration of B-site cations (Ta and Nb) in the ferroelectric phase. Ta is found to have an off-center displacement of about 0.02Å along [001]. The off-center displacement of Nb is much larger than that of Ta, thus it makes a major contribution to the occurrence of the ferroelectric instability.
|
|
Influence of Fe in the local Structure of Perovskite Compound La2/3Cal/3Fel-xMnxO3
WE Long, WANG Yun-Bo, WANG Hui-Yao, YUE Yong, WANG Tian-Min, ZHANG Tian-Bao, CAO Guo-Hui,
Chin. Phys. Lett. 2000, 17 (6):
446-447
.
The ceramic samples with nominal composition of La2/3Cal/3Mnl-xFexO3 (0.01 ≤ x ≤ 0.20) were prepared by solid state reaction method. The effect of Fe doping on the Mn site was measured by the positron annihilation technique and Mössbauer spectroscopy. Upon doping, no appreciable structure change and electronic structure change in Mn-O plane were observed in the series of compounds. The Mössbauer parameters show that the iron probe has stable 3+ valance with the high spin state in all samples. Moreover, by examining the shape of the spectra, the tendency can be found that the isomer shift and quadruploe splitting increase with the increasing Fe+3 content. This phenomenon shows the local lattice distortion and the localization of d-electrons with the increasing Fe-doping content.
|
|
Preparation of Si Nanocrystals Using Anodic Porous Alumina Template Formed on Silicon Substrate
WU Jun-Hui, PU Lin, ZOU Jian-Ping, MEI Yong-Feng, ZHU Jian-Min, BAO Xi-Mao
Chin. Phys. Lett. 2000, 17 (6):
451-453
.
A novel technique to extend template application of anodic porous alumina to Si has been reported. First, porous alumina template about 400nm thick was prepared on silicon substrate by anodizing thin aluminum film with high purity of 99.99% in 15 wt.% sulfuric acid under a constant voltage of 20 V and at an electrolyte temperature of 5oC. Then, amorphous Si layer approximately 50nm in thickness was deposited onto the surface of template by using electron beam evaporation technique followed by an Xe ion beam bombardment, upon which as-coated Si layer at the pore mouth could be removed into pores smoothly. Three runs were performed by repeating above process of deposition and post bombardment. Finally, samples were annealed at 800oC for 30min in nitrogen. Transmission electron microscopy and x-ray diffraction analysis reveal Si nanocrystals with a size of 15-20nm being formed in the pores of template.
|
|
Organic Light-Emitting Diodes Based on New Oxadiazole and Pyrazoline Derivatives
ZHANG Zhi-Ming, ZHANG Rui-Feng, WU Fang, MA Yu-Guang, LI Guo-Wen, TIAN Wen-Jing, SHEN Jia-Cong
Chin. Phys. Lett. 2000, 17 (6):
454-456
.
The bilayer heterojunction devices were fabricated successfully by using a novel oxadiazole derivative: 2, 2'- (2,5-thiophenediyl) bis (5-(4-methyl) phenyl-l,3,4-oxadiazole) (T-OXD) as the electron-transporting layer (ETL) and a pyrazoline derivative:l-phenyl-3-(dimethylamino)styry1-5-(p(dimethylamino) pheny1)pyrazoline (PDP) as the light-emitting layer and the hole-transporting layer. The emission at 500nm was derived from PDP layer. In comparison with the bilayer device of tris (8-hydroxyquinoline) aluminum (Alq) as the ETL, the luminous efficiency of the PDP/T-OXD heterojunction device was enhanced by 104 times.
|
|
Positron Annihilation Mechanism Correlated with Microstructure of C60-Contained Chitosan
DAI Yi-Qun, HE Chun-Qing, LI Shi-Qing, FANG Peng-Fei, CHEN Yuan-Yin, WANG Shao-Jie
Chin. Phys. Lett. 2000, 17 (6):
457-459
.
Positron annihilation lifetime spectra measurements were performed on C60-containing chitosan as a function of temperature ranging from 290 to 380K. Both the ortho-positronium annihilation lifetime т3 and its intensity I3 increase with increasing temperature, however, the values of I3 in C60-containing chitosan are smaller than that in pure chitosan, and the slope of т3 with temperature is also suppressed after C60 linked. The existing three models for positron annihilation in polymer have been compared to analyze the experiment result. It is realized that only the spur reaction model, combined with the free volume model, can explain it satisfactorily. The ortho-positronium lifetime and intensity were affected by the local physicochemical environment of material, i.e., free-volume structure, electron scavenging and trapping sites, etc. The linked C60 that play a significant chemical inhibition and quenching role on positronium formation and annihilation is first observed. The microstructure change brought by C60 group has also been discussed.
|
29 articles
|