|
Anomalous Photofragmentation of Fullerene Doped in Silica Aerogel─Enhanced Formation of Odd-Numbered “Fullerene” Fragments
KONG Qing-Yu, ZHAO Li, ZHUANG Jun, QIAN Shi-Xiong, LI Yu-Fen, WANG Jue
Chin. Phys. Lett. 2001, 18 (12):
1578-1581
.
Photofragmentation of fullerene-doped silica aerogels has been investigated by the excimer laser ablation reflectron time-of-flight mass spectrometric technique. Great enhancement in the formation of odd-numbered ‘fullerene’fragments has been observed in the negative ion channel for the chemically doped aerogel sample. Generally, odd-numbered species C57, C55, C53, C51 appeared in the mass spectra. Under optimal experimental conditions C55 can be even more intense than the neighboring even-numbered carbon clusters. In contrast, for the physically doped sample, just like pristine C60, only weak odd-numbered fragments were observed. In the positive-ion channel, the behaviour of all these samples is similar, no odd-numbered species was ever detected. A mechanism related to the interaction between the fullerene dopant and the silica aerogel host is suggested for the anomalous enhancement of the odd-numbered cluster formation. A preliminary discussion on the structures of the odd-numbered ‘fullerene’fragments is given.
|
|
More Magic Numbers in Titanium-Carbon Anion Clusters: Can This
Be Explained by Any Structural Growth Pattern?
ZHAI Hua-Jin, LIU Bing-Chen, ZHOU Zheng-Wen, ZHOU Ru-Fang, NI Guo-Quan, XU Zhi-Zhan
Chin. Phys. Lett. 2001, 18 (12):
1582-1585
.
Titanium-carbon anion clusters with a mass range up to 1800 amu have been generated in a Smalley-type cluster source involving a target rod composed of titanium and graphite powders, and have been analysed by time-of-flight mass spectrometry. In the lower mass range (up to 1200 amu), our mass spectrum reproduces all the magic numbers, which have been reported previously, i.e., Ti3C-8, Ti6C-13, Ti7C-13, Ti9C-15, Ti13C-22, and Ti14C-24, in spite of many differences in experimental conditions. In the higher mass range (1200-1800 amu), we observe new magic numbers at Ti15C-26, Ti20C-33/Ti20C-34 and Ti25C-42, which cannot be accounted for by the previously proposed structural growth patterns. All the magic and local maximum TixC-y peaks have a metal-to-carbon ratio of approximately 1:1.7. The present results suggest a further complexity to the structural growth patterns of the transition metal-carbon mixed cluster systems.
|
|
Yb3+-Doped Double-Clad Fiber Laser Pumped by Rectangular Inner Cladding
NING Ding, LI Yi-Gang, HUANG Bang-Cai, SUN Jian-Jun, LÜ, Ke-Cheng, YUAN Shu-Zhong, DONG Xiao-Yi
Chin. Phys. Lett. 2001, 18 (12):
1592-1594
.
A novel Yb3+-doped double-clad silica fiber with rectangular inner cladding was designed and developed by using the modified chemical vapour deposition process, solution-doping and optical machining altogether. The dimension of inner cladding is 100 x 70μm, and Yb3+-doped concentration in the core is about 0.24wt.%. The operation of the fiber laser pumped by inner cladding is reported. The threshold of the laser is 34mW. When the pump power launched is 141mW, the laser output is 84mW at the wavelength 1075.6nm, and the slope efficiency is 77%.
|
|
Particle Simulation Research on the Detail Process of Bubble Generatio
MA Yan-Yun, CHANG Wen-Wei, YIN Yan, CAO Li-Hua, YUE Zong-Wu
Chin. Phys. Lett. 2001, 18 (12):
1628-1631
.
The detail process of bubble generation in laser-plasma interaction has been studied by particle simulation. During the interaction between laser and plasma, a strong electrostatic field caused by charge separation is observed, whose structure looks like a potential well. Electrons are accelerated to 10MeV within some tens of femtoseconds when the laser intensity is 5 x 1018W/cm2. After manya electrons escape from the potential-well-like structure, electron cavitons are generated. Because of laser filamentation, the intensity of the laser becomes very asymmetric, the caviton structure is squeezed and deformed, and then electron bubbles are generated, which result in ion bubble formation at last. It is the electron caviton and laser beam filamentation that cause bubble generation. The 10MeV superthermal electron generation accompanied with the electron caviton is attributed to E▽.E heating, which is a locally oscillating electron heating mechanism.
|
|
Sound Velocities in Porous Iron Shocked to 177GPa and the
Implications for Shock Melting
LI Xi-Jun, ZHOU Xian-Ming, WANG Fan-Hou, LIU Fu-Sheng, GONG Zi-Zheng, JING Fu-Qian,
Chin. Phys. Lett. 2001, 18 (12):
1632-1634
.
Sound velocities in shock-loaded solids are not only important to determine bulk moduli of solids at high pressures, but also crucial to inform the shock melting of solids upon loading. In this letter, we first report on shock melting of porous solids at high pressures by measuring sound velocities in the porous iron of average density 6.90g/cm3 in the pressure range of 110-180GPa. The measured sound velocity softens at pressures from 122 to 156Gpa, which may be attributed to shock melting of the porous iron.
|
|
Origin of the Novel Magnetoresistance Oscillation of the Two-Dimensional Electron Gas in AlxGa1-xN/GaN Heterostructures
ZHENG Ze-Wei, SHEN Bo, JIANG Chun-Ping, ZHANG Rong, SHI Yi, HENG You-Dou, ZHENG Guo-Zhen, GUO Shao-Ling, CHU Jun-Hao
Chin. Phys. Lett. 2001, 18 (12):
1641-1643
.
In the magnetotransport measurements of the two-dimensional electron gas (2DEG) in modulation-doped Al0.22Ga0.78N/GaN heterostructures, a new magnetoresistance oscillation of the 2DEG is observed at low magnetic fields when the Al0.22Ga0.78N layer on GaN is under partially relaxed. It is thought that the misfit dislocations induced by the partialy relaxed Al0.22Ga0.78N layer modulate the distribution of the piezoelectric polarization-induced charges at the Al0.22Ga0.78N/GaN heterointerface, and thus produce a strong modulation-potential at the heterointerface. The strong modulation-potential results in the novel magnetoresistance oscillation of the 2DEG at low magnetic fields.
|
|
New Features of the Coercivity in Exchange-Coupled Ni81Fe19/CoO Bilayers
CAI Jian-Wang, LAI Wu-Yan
Chin. Phys. Lett. 2001, 18 (12):
1651-1654
.
The coercivity behaviour of the Ni81Fe19 film exchange-coupled with an antiferromagnetic CoO underlayer has been investigated systematically. It has been found that the coercivity is greatly enhanced not only at the easy axis but also at the hard axis direction when the temperature is below the Néel temperature of CoO, Also, the thickness dependence of coercivity at low temperature follows the scaling relation as 1/tαNiFe with α = 2.5 at the hard axis, which is quite in contrast with the case of the easy axis, i.e., α =1.5, predicted theoretically and verified experimentally previously. The increase of the temperature leads to the decrease of the coercivity at both the easy and hard axes, but the scaling relations are held except the narrow region just below the Néeel temperature of CoO, at which the coercivity varies as 1/tαNiFe with α = 1.0 for both the easy and hard axes. Based upon Hoffmann's ripple theory and Malozemoff's random field model, a simple interpretation on the experiment findings is presented.
|
|
Optical Absorption in SiGe/Si Quantum Well Structures Created by
Subband Transitions
YANG Yu, MAO Xu, YANG Hong-Wei, ZHOU Wei, ZHOU Zhen-Lai, LIU Huan-Lin, WANG Xun
Chin. Phys. Lett. 2001, 18 (12):
1655-1657
.
The absorption in Si1-xGex/Si multiple quantum-well structures is measured. Several separated well absorption peaks corresponding to both intersubband and intervalance band transitions in the samples are observed. In the normal incidence, two broadband peaks are attributed to intervalence band transitions HH0-SO0(2.5μm), HH0-LH0(~ 3μm), respectively. Using 45°incidence of unpolarized light, both the intervalance band transitions and intersubband transitions are observed. The intervalance band transitions (HH0-LH0) are Ge composition dependent, but the intersubband transitions, HH0-HH1(5.9μm) and HH0-HH2(4.3μm), are not sensitive to the Ge composition.
|
|
An Organic Quantum-Well Electroluminescent Device with
Enhanced Performance
YANG Kai-Xia, GAO Wen-Bao, LIU Hong-Yu, LI Chuan-Nan, ZHAO Yi,
LIU Shi-Yong, HUANG Jing-Song
Chin. Phys. Lett. 2001, 18 (12):
1658-1659
.
An organic electroluminescent (EL) device has been constructed with double quantum-well structure consisting of N,N'-bis-(1-naphthl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine (NPB) doped with 5,6,11,12-tetraphenylnaphtha- cene (rubrene) as a potential well and emitter, undoped NPB as a barrier potential. The maximum EL efficiency and brightness reach to 5.6cd/A and 40000cd/m2, respectively. Most meaningfully, with the increase of the drive voltage, the EL efficiency (cd/A) declines very slowly after reaching its maximum, almost independent of the drive voltage in a wide range from 5 to 13V. The characteristic may be useful in improvement of the lifetime of the device.
|
|
High-Velocity H2O Masers Associated Massive Star Formation
Regions
XU Ye, JIANG Dong-Rong, ZHENG Xing-Wu, GU Min-Feng, YU Zhi-Yao, PEI Chun-Chuan
Chin. Phys. Lett. 2001, 18 (12):
1663-1665
.
We report on the results of 12CO (1-0) emission associated with H2O masers and massive star formation regions to identify high-velocity H2O masers. Several masers have a large blue-shift, even up to 120km.s-1, with respect to the CO peak, but no large redshifted maser appears. This result suggests that high-velocity H2O masers can most probably occur in high mass star-forming regions and quite a number of masers stem from the amplifications of a background source, which may enable those undetectable weak masers to become to an observable level.
|
37 articles
|