CROSS-DISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY |
|
|
|
|
Effects of Substrate Temperature on Properties of Transparent Conductive Ta-Doped TiO$_{2}$ Films Deposited by Radio-Frequency Magnetron Sputtering |
Yang Liu1,2, Qian Peng1, Zhong-Pin Zhou1, Guang Yang1** |
1School of Physics, Huazhong University of Science and Technology, Wuhan 430074 2School of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000
|
|
Cite this article: |
Yang Liu, Qian Peng, Zhong-Pin Zhou et al 2018 Chin. Phys. Lett. 35 048101 |
|
|
Abstract Ta-doped titanium dioxide films are deposited on fused quartz substrates using the rf magnetron sputtering technique at different substrate temperatures. After post-annealing at 550$^{\circ\!}$C in a vacuum, all the films are crystallized into the polycrystalline anatase TiO$_{2}$ structure. The effects of substrate temperature from room temperature up to 350$^{\circ\!}$C on the structure, morphology, and photoelectric properties of Ta-doped titanium dioxide films are analyzed. The average transmittance in the visible region (400–800 nm) of all films is more than 73%. The resistivity decreases firstly and then increases moderately with the increasing substrate temperature. The polycrystalline film deposited at 150$^{\circ\!}$C exhibits a lowest resistivity of $7.7\times10^{-4}$ $\Omega\cdot$cm with the highest carrier density of $1.1\times10^{21}$ cm$^{-3}$ and the Hall mobility of 7.4 cm$^{2}\cdot V^{-1}$ $s^{-1}$.
|
|
Received: 09 October 2017
Published: 13 March 2018
|
|
|
|
Fund: Supported by the National Natural Science Foundation of China under Grant No 11374114. |
|
|
[1] | Gordon R G 2000 Mater. Res. Bull. 25 52 | [2] | Hosono H, Ohta H, Orita M et al 2002 Vacuum 66 419 | [3] | Kim D H, Lee S, Park J H et al 2012 Sol. Energy Mater. Sol. Cells 96 276 | [4] | Fortunato E, Barquinha P, Pimentel A et al 2005 Thin Solid Films 487 205 | [5] | Tahar R, Ban T, Ohya Y et al 1998 J. Appl. Phys. 83 2631 | [6] | Mryasov O N and Freeman A J 2001 Phys. Rev. B 64 233111 | [7] | Calnan S and Tiwari A N 2010 Thin Solid Films 518 1839 | [8] | Hitosugi T, Ueda A, Furubayashi Y et al 2007 Jpn. J. Appl. Phys. 46 L86 | [9] | Furubayashi Y, Hitosugi T, Yamamoto Y et al 2005 Appl. Phys. Lett. 86 252101 | [10] | Wan G, Wang S, Zhang X et al 2015 Appl. Surf. Sci. 357 622 | [11] | Hitosugi T, Yamada N, Nakao S et al 2010 Phys. Status Solidi A 207 1529 | [12] | Hitosugi T, Furubayashi Y, Ueda A et al 2005 Jpn. J. Appl. Phys. Part 2 44 L1063 | [13] | Gillispie M A, Van Hest M F A M, Dabney M S et al 2007 J. Mater. Res. 22 2832 | [14] | Mazzolini P, Gondoni P, Russo V et al 2015 J. Phys. Chem. C 119 6988 | [15] | Huy H A, Aradi B, Frauenheim T et al 2012 J. Appl. Phys. 112 16103 | [16] | Manole A V, Dobromir M, Gîrtan M et al 2013 Ceram. Int. 39 4771 | [17] | Fallah M, Zamani M M, Rahimi R et al 2014 Appl. Surf. Sci. 316 456 | [18] | Battiston G A, Gerbasi R, Gregori A et al 2000 Thin Solid Films 371 126 | [19] | Long H, Yang G, Chen A et al 2008 Thin Solid Films 517 745 | [20] | Tucker R T, Beckers N A, Fleischauer M D et al 2012 Thin Solid Films 525 28 | [21] | Wang S, Hsu Y, Lee R et al 2004 Appl. Surf. Sci. 229 140 | [22] | Sato Y, Akizuki H, Kamiyama T et al 2008 Thin Solid Films 516 5758 | [23] | Chen C, Ji Y, Gao X Y et al 2012 Acta Phys. Sin. 61 036104 (in Chinese) | [24] | Lu L, Guo M, Thornley S et al 2016 Sol. Energy Mater. Sol. Cells 149 310 | [25] | Ok K, Park Y, Chung K et al 2013 Appl. Phys. Lett. 103 213501 | [26] | Furubayashi Y, Yamada N, Hirose Y et al 2007 J. Appl. Phys. 101 093705 | [27] | Seeger S, Ellmer K, Weise M et al 2016 Thin Solid Films 605 44 | [28] | Kim H, Osofsky M, Prokes S M et al 2013 Appl. Phys. Lett. 102 171103 | [29] | Wagner C D, Riggs W M, Davis L E et al 1978 Handbook of X-ray Photoelectron Spectroscopy (Eden Prairie MN: Perkin-Elmer) | [30] | Song D Y, Aberle A G and Xia J 2002 Appl. Surf. Sci. 195 291 | [31] | Ma Q, Ye Z, He H et al 2007 Vacuum 82 9 | [32] | Hong R J, Jiang X, Szyszka B et al 2003 Appl. Surf. Sci. 207 341 | [33] | Zhu K, Yang Y, Song W et al 2015 Mater. Lett. 145 279 | [34] | Neubert M, Cornelius S, Fiedler J et al 2013 J. Appl. Phys. 114 083707 | [35] | Tseng Z L, Chen L C, Tang J F et al 2017 J. Electro. Mater. 46 1476 | [36] | Coutts T J, Young D L and Li X N 2000 Mater. Res. Bull. 25 58 |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|