ATOMIC AND MOLECULAR PHYSICS |
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Isotopic Analysis to Determine All the Molecular Constants of O2+ in the A–X System |
SHAO Xu-Ping1, WANG Qing-Hui1, WU Yan-Dan2, WU Ling3, YANG Xiao-Hua1,4** |
1School of Science, Nantong University, Nantong 226007 2School of Science, Hanshan Normal College, Chaozhou 521000 3Institute of Materials Physics, Hangzhou Dianzi University, Hangzhou 310018 4State Key Laboratory of Precision Spectroscopy, East China Normal University, Shanghai 200062
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Cite this article: |
SHAO Xu-Ping, WANG Qing-Hui, WU Yan-Dan et al 2014 Chin. Phys. Lett. 31 113301 |
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Abstract The linear correlated constants AD (centrifugal correction of the spin-orbit coupling constant) and γ (the spin-rotation constant) involved in the second negative (A2Πu-X2Πg) system of O2+ are determined by nonlinear least-squares fitting the spectra of 16O2+ and 18O2+ using the isotopic effect. In addition, the molecular constants of the other O2+ isotopologues are predicted.
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Published: 28 November 2014
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PACS: |
33.15.Mt
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(Rotation, vibration, and vibration-rotation constants)
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33.15.Pw
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(Fine and hyperfine structure)
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33.20.Vq
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(Vibration-rotation analysis)
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