Raman Spectra of Deuterated Potassium Dihydrogen Phosphate Crystals with Different Degrees of Deuteration

doi:10.1088/0256-307X/30/6/067804

Chin. Phys. Lett.

2013, Vol. 30

Issue (6): 067804 DOI: 10.1088/0256-307X/30/6/067804

CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES

Raman Spectra of Deuterated Potassium Dihydrogen Phosphate Crystals with Different Degrees of Deuteration

LIU Bao-An¹, ZHOU Hai-Liang^1,2, ZHANG Qing-Hua³, XU Ming-Xia¹, JI Shao-Hua¹, ZHU Li-Li¹, ZHANG Li-Song¹, LIU Fa-Fu¹, SUN Xun^1**, XU Xin-Guang¹

¹State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100
²School of Information Science and Engineering, Shandong Agricultural University, Taian 271018
³Chengdu Fine Optical Engineering Research Centre, Chengdu 610041

Cite this article:

LIU Bao-An, ZHOU Hai-Liang, ZHANG Qing-Hua et al 2013 Chin. Phys. Lett. 30 067804

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Abstract The polarized Raman spectra of deuterated potassium dihydrogen phosphate crystals with different deuterium concentrations are measured. With the increasing deuterium concentration, the Raman peaks which are assigned as the internal vibrations of the (H/D)₂PO₄^? anion shift to lower wavenumbers. This red-shift contributes to the decrease in the bonding force of the P–O bond as a result of the substitution of deuterium for hydrogen. Moreover, the intensity of the strongest peak of these crystals decreases first, and reaches the minimum value while the mole percentage of the deuterium content in the crystal is about 74%. After that, the intensity increases with the increase of the deuterium concentration in the crystal.

Received: 22 February 2013 Published: 31 May 2013

PACS:

78.30.-j

(Infrared and Raman spectra)

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https://cpl.iphy.ac.cn/10.1088/0256-307X/30/6/067804 OR https://cpl.iphy.ac.cn/Y2013/V30/I6/067804

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	LIU Bao-An
	ZHOU Hai-Liang
	ZHANG Qing-Hua
	XU Ming-Xia
	JI Shao-Hua
	ZHU Li-Li
	ZHANG Li-Song
	LIU Fa-Fu
	SUN Xun
	XU Xin-Guang

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