ATOMIC AND MOLECULAR PHYSICS |
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Collision Energies Effect on Stereodynamics for Ne+H2+→NeH++H Reaction |
XIAO Jing, YANG Chuan-Lu**, WANG Mei-Shan, MA Xiao-Guang
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School of Physics, Ludong University, Yantai 264025
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Cite this article: |
XIAO Jing, YANG Chuan-Lu, WANG Mei-Shan et al 2011 Chin. Phys. Lett. 28 013101 |
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Abstract Vector correlation between reagents and products for the reaction Ne+H2+→NeH++H is studied using quasi−classical trajectory method at different collision energies on a new surface constructed by Lv et al.[J. Chem. Phys.132 (2010) 014303] The results of angular distributions P(θr) and P(φr) show that the product rotational angular momentum is not only aligned, but also oriented along the direction perpendicular to the scattering plane. The four polarization−dependent generalized differential cross sections show that the scatting direction of product NeH+ is significantly affected by the collision energy.
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Keywords:
31.15.Ap
34.50.Lf
31.15.Xv
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Received: 08 October 2010
Published: 23 December 2010
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PACS: |
31.15.ap
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(Polarizabilities and other atomic and molecular properties)
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34.50.Lf
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(Chemical reactions)
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31.15.xv
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(Molecular dynamics and other numerical methods)
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[1] Klein F S and Friedman L 1964 J. Chem. Phys. 41 1789
[2] Bilotta R M and Farrar J M 1981 J. Chem. Phys. 75 1776
[3] Pijkeren D van, Boltjes E, Eck J van and Niehaus A 1984 Chem. Phys. 91 293
[4] Herman Z and Koyano I 1987 J. Chem. Soc. Faraday Trans. 283 127
[5] Zhang T, Qian X M, Tang X N, Ng C Y, Chiu Y, Levandier D J, Miller J S and Dressler R A 2003 J. Chem. Phys. 119 10175
[6] Kress J D, Walker R B, Hayes E F and Pendergast P 1994 J. Chem. Phys. 10 2728
[7] Gilibert M, Blasco R M, González M, Giménez X, Aguilar A, last I and Baer M 1997 J. Phys. Chem. A 101 6821
[8] Gilibert M, Giménez X, Huarte-Larrañaga F, González M, Aguilar A, Last I and Baer M 1999 J. Chem. Phys. 110 6278
[9] Huarte-Larrañaga F, Giménez X, Lucas J M, Aguilar A and Launay J M 1999 Phys. Chem. Chem. Phys. 1 1125
[10] Huarte-Larrañaga F, Giménez X, Lucas J M, Aguilar A and Launay J M 2000 J. Phys. Chem. A 104 10227
[11] Mayneris J, Sierra J D and González M 2008 J. Chem. Phys. 128 194307
[12] Mayneris-Perxachs J and González M 2009 J. Phys. Chem. A 113 4105
[13] Pendergast P, Heck J M, Hayes E F and Jaquet R 1993 J. Chem. Phys. 98 4543
[14] Lv S J, Zhang P Y, Han K L and He G Z 2010 J. Chem. Phys. 132 014303
[15] Chu T S, Zhang Y and Han K L 2006 Int. Rev. Phys. Chem. 25 201
[16] Han K L, He G Z and Lou N Q 1993 Chin. Chem. Lett. 4 517
[17] Li W L, Wang M S, Yang C L, Ma X G, Wang D H and Liu W W 2007 Chem. Phys. Lett. 445 125
[18] Zhang W Q, Cong S L, Zhang C H, Xu X S and Chen M D 2009 J. Phys. Chem. A 113 4192
[19] Li R J, Han K L, Li F E, Lu R C, He G Z and Luo N Q 1994 Chem. Phys. Lett. 220 281
[20] Han K L, He G Z and Lou N Q 1996 J. Chem. Phys. 105 8699
[21] Zhang W Q, Li Y Z, Xu X S and Chen M D 2010 Chem. Phys. 367 115
[22] Chu T S and Han K L 2008 Phys. Chem. Chem. Phys. 10 2431
[23] Chen M D, Han K L and Lou N Q 2002 Chem. Phys. Lett. 357 483
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