| ATOMIC AND MOLECULAR PHYSICS |
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A Time-Dependent Wavepacket Method for Photodissociation Dynamics of Triatomic Molecule |
| Mohammad Noh Daud1, Gabriel G. Balint-Kurti2 |
| 1Department of Chemistry, University of Malaya, Kuala Lumpur 50603, Malaysia2School of Chemistry, University of Bristol, Bristol BS8 1TS, UK |
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| Cite this article: |
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Mohammad Noh Daud, Gabriel G. Balint-Kurti 2009 Chin. Phys. Lett. 26 073302 |
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Abstract We report a time-dependent quantum wavepacket theory employed to interpret the photoabsorption spectrum of the N2O molecule in terms of the nuclear motion on the upper 21A' and 11A'' potential energy surfaces. The N2-O bond breaks upon excitation leading to dissociation. The total angular momentum is treated correctly taking into account the vector property of the electric field of the exciting radiation.
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| Keywords:
33.20.Lg
31.70.-f
31.15.Ar
02.70.-c
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Received: 09 July 2008
Published: 02 July 2009
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| PACS: |
33.20.Lg
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(Ultraviolet spectra)
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31.70.-f
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(Effects of atomic and molecular interactions on electronic structure)
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31.15.Ar
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02.70.-c
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(Computational techniques; simulations)
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