| CROSS-DISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY |
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Effects of Raw Material Content on Efficiency of TiN Synthesized by Reactive Ball Milling Ti and Urea |
| SUN Jin-Feng, LI Xiao-Pu, LIANG Bao-Yan, ZHAO Yu-Cheng, WANG Ming-Zhi |
| State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 |
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| Cite this article: |
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SUN Jin-Feng, LI Xiao-Pu, LIANG Bao-Yan et al 2009 Chin. Phys. Lett. 26 078102 |
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Abstract Ti and urea mixed according to the molar ratios of 2:1, 3:1 and 4:1 are milled under the same condition. The structures of the as-synthesized powders are analyzed by an x-ray diffractometer (XRD). The decomposed temperature of the urea and the products decomposed are characterized by differential scanning calorimetry (DSC) and thermogravimetry analysis-Fourier transform infrared (TG-FTIR) spectrometry. The results show that the reaction progress is a diffusion reaction. The efficiency of TiN synthesized by reactive ball milling can be increased by increasing the content of Ti. The reactive ball milling time decreases from more than 90h to 40h corresponding to the content ratio between Ti and urea increasing from 2:1 to 4:1. Ammonia gas (NH3) and cyanic acid (HNCO), the decomposed products of urea, react with the refined Ti to form TiN. The grain refinement of Ti has a significant effect on the efficiency of reactive ball milling.
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| Keywords:
81.05.Je
81.20.Ev
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Received: 19 February 2009
Published: 02 July 2009
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| PACS: |
81.05.Je
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(Ceramics and refractories (including borides, carbides, hydrides, nitrides, oxides, and silicides))
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81.20.Ev
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(Powder processing: powder metallurgy, compaction, sintering, mechanical alloying, and granulation)
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