Chin. Phys. Lett.  2004, Vol. 21 Issue (3): 540-543    DOI:
Original Articles |
Structural and Transport Properties for Al- and Fe-Doping La0.67Ca0.33MnO3 Perovskite Manganese
CUI Yu-Jian1;JIA Guang-Qiang2;HAN Yan-Bing1;LI Jin-Bo3;WANG Xin-Yan2;GE Hong-Liang1;CAO Shi-Xun2;ZHANG Jin-Cang2
1Department of Physics, Chinese Institute of Metrology, Hangzhou 310018 2Department of Physics, Shanghai University, Shanghai 200436 3Department of Physics, Henan Polytechnic Institute, Nanyang 473009
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CUI Yu-Jian, JIA Guang-Qiang, HAN Yan-Bing et al  2004 Chin. Phys. Lett. 21 540-543
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Abstract The effects of Al and Fe ion doping in Mn sites was studied for the colossal La0.67Ca0.33MnO3 magnetoresistance material. It was found that when the Fe-doping amount x increases, the crystal cell structure has no obvious change, but the crystal cell volume decrease monotonically for Al-doping. Both resistances increase rapidly and the insulator-metal transition temperature moves to lower temperature and decreases linearly with Al-doping. The area for Al-doping is broader than Fe. At small amount of Al-doping, the resistance satisfy the metal transport property when T < TIM. The characteristic of the transport behaviour for Al- and Fe-doping can be explained by terminating the double exchange channel of Mn3+-O2--Mn4+.
Keywords: 75.30.Vn      75.30.Kz     
Published: 01 March 2004
PACS:  75.30.Vn  
  75.30.Kz (Magnetic phase boundaries (including classical and quantum magnetic transitions, metamagnetism, etc.))  
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https://cpl.iphy.ac.cn/       OR      https://cpl.iphy.ac.cn/Y2004/V21/I3/0540
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CUI Yu-Jian
JIA Guang-Qiang
HAN Yan-Bing
LI Jin-Bo
WANG Xin-Yan
GE Hong-Liang
CAO Shi-Xun
ZHANG Jin-Cang
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