Chin. Phys. Lett.  2010, Vol. 27 Issue (8): 087202    DOI: 10.1088/0256-307X/27/8/087202
CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES |
Kondo Effect in Self-Assembled Manganese Phthalocyanine Monolayer on Pb Islands

JI Shuai-Hua1,2, FU Ying-Shuang1,2, ZHANG Tong1,2, CHEN Xi2, JIA Jin-Feng2, XUE Qi-Kun2, MA Xu-Cun1

1Institute of Physics, Chinese Academy of Sciences, Beijing 100190 2Department of Physics, Tsinghua University, Beijing 100084
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JI Shuai-Hua, FU Ying-Shuang, ZHANG Tong et al  2010 Chin. Phys. Lett. 27 087202
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Abstract

The Kondo effect in two-dimensional manganese phthalocyanine (MnPc) self-assembled monolayer films on Pb(111) islands is studied by low-temperature scanning tunneling microscopy. Variation of the Kondo temperature from 50 K to 300 K at different molecule adsorption sites is revealed. It is shown that the variation is mainly due to the change in the width of d orbital, rather than the shift of its energy. The two-dimensional dI/dV mapping reveals the periodic modulation of the Kondo resonance in the self-assembled MnPc monolayer.

Keywords: 72.15.Qm      68.37.Ef      68.55.-a     
Received: 06 April 2010      Published: 28 July 2010
PACS:  72.15.Qm (Scattering mechanisms and Kondo effect)  
  68.37.Ef (Scanning tunneling microscopy (including chemistry induced with STM))  
  68.55.-a (Thin film structure and morphology)  
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https://cpl.iphy.ac.cn/10.1088/0256-307X/27/8/087202       OR      https://cpl.iphy.ac.cn/Y2010/V27/I8/087202
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JI Shuai-Hua
FU Ying-Shuang
ZHANG Tong
CHEN Xi
JIA Jin-Feng
XUE Qi-Kun
MA Xu-Cun
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