Chin. Phys. Lett.  2000, Vol. 17 Issue (6): 448-450    DOI:
Original Articles |
Thermal Expansion of CsNiCI3 by Electron Paramagnetic Resonance and Optical Absorption Spectra
GUO Sheng-Li1,2;ZHANG Yong2;YOU Xiao-Zeng2;MIN Nai-Ben1
1State Key Laboratory of Solid State Microstructures and Department of Physics, 2Institute of Coordination Chemistry, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093
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GUO Sheng-Li, ZHANG Yong, YOU Xiao-Zeng et al  2000 Chin. Phys. Lett. 17 448-450
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Abstract Electron paramagnetic resonance (EPR) measurement of CsNiCl3 compound has been performed at 192 GHz in the temperature range from 300 to 5K, along the axes of main g tensor. The energy levels and the g-factors are calculated. The linear thermal expansion coefficient ( 2.77x10-5 K-1 ) for the Ni2+-CI- bond distance is studied by combining EPR and optical absorption spectra with changing temperature.

Keywords: 76.30.Fc      71.70.Ch     
Published: 01 June 2000
PACS:  76.30.Fc (Iron group (3d) ions and impurities (Ti-Cu))  
  71.70.Ch (Crystal and ligand fields)  
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https://cpl.iphy.ac.cn/       OR      https://cpl.iphy.ac.cn/Y2000/V17/I6/0448
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