| CROSS-DISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY |
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Ferroelectric Ceramic Materials Enable High-Performance Organic-Inorganic Composite Electrolytes in Solid-State Lithium Metal Batteries |
| Jing-Yuan Ma1†, Yu-Li Huang2†, Han-Jie Zhou1, Yuan-Yuan Wang1, Jian-Gang Li1, Xi-Qian Yu2, Hong Li2*, and Yan Li1* |
1College of New Materials and Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102627, China
2Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
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| Cite this article: |
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Jing-Yuan Ma, Yu-Li Huang, Han-Jie Zhou et al 2024 Chin. Phys. Lett. 41 078202 |
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Abstract Compared to commercial lithium-ion batteries, all-solid-state batteries can greatly increase the energy density, safety, and cycle life of batteries. The development of solid-state electrolyte with high lithium-ion conductivity and wide electrochemical window is the key for all-solid-state batteries. In this work, we report on the achievement of high ionic conductivity in the PAN/LiClO$_{4}$/BaTiO$_{3}$ composite solid electrolyte (CSE) prepared by solution casting method. Our experimental results show that the PAN-based composite polymer electrolyte with 5 wt% BaTiO$_{3}$ possesses a high room-temperature lithium-ion conductivity ($9.85\times 10^{-4}$ S$\cdot$cm$^{-1})$, high lithium-ion transfer number (0.63), wide electrochemical window (4.9 V vs Li$^{+}$/Li). The Li$|$Li symmetric battery assembled with 5 wt% BaTiO$_{3}$ can be stably circulated for 800 h at 0.1 mA$\cdot$cm$^{-2}$, and the LiFePO$_{4}|$CSE$|$Li battery maintains a capacity retention of 86.2% after 50 cycles at a rate of 0.3 C. The influence of BaTiO$_{3}$ ceramic powder on the properties of PAN-based polymer electrolytes is analyzed. Our results provide a new avenue for future research in the all-solid-state lithium battery technology.
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Received: 27 March 2024
Published: 24 July 2024
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