CONDENSED MATTER: STRUCTURE, MECHANICAL AND THERMAL PROPERTIES |
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Interception of Layered LP-N and HLP-N at Ambient Conditions by Confined Template |
Dong-Xue Wang1, Jing Fu2, Yi Li3, Zhen Yao1*, Shuang Liu1*, and Bing-Bing Liu1* |
1State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130012, China 2Basic Science Department, Jilin Institute of Architecture and Technology, Changchun 130000, China 3College of Science, Liaoning University of Technology, Jinzhou 121000, China
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Cite this article: |
Dong-Xue Wang, Jing Fu, Yi Li et al 2024 Chin. Phys. Lett. 41 036101 |
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Abstract We propose a feasible strategy of intercepting the layered polymeric nitrogen (LP-N) and hexagonal layered polymeric nitrogen (HLP-N) at ambient conditions by using the confinement templates. The stable mechanism of confined LP-N and HLP-N at ambient conditions is revealed, namely the synergistic effect of charge transfer and vdW confinement effect. The influence rule of interlayer spacing on the stability of LP-N is revealed. Most importantly, the nitrogen content and energy density of recoverable LP-N@graphene (70.59%, 8.15 kJ/g), LP-N@h-BN (70.59%, 7.96 kJ/g), HLP-N@graphene (68.97%, 9.31 kJ/g), and HLP-N@h-BN (69.57%, 8.05 kJ/g) refresh the new record for the confinement polynitrogen system.
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Received: 04 December 2023
Published: 12 March 2024
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PACS: |
67.85.-d
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(Ultracold gases, trapped gases)
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03.75.Mn
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(Multicomponent condensates; spinor condensates)
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05.30.Jp
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(Boson systems)
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05.30.Rt
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(Quantum phase transitions)
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