| CONDENSED MATTER: STRUCTURE, MECHANICAL AND THERMAL PROPERTIES |
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Li Plating on Carbon Electrode Surface Probed by Low-Field Dynamic Nuclear Polarization $^{7}$Li NMR |
| Zhekai Zhang1,2, Jiyu Tian3, Junfei Chen1, Yugui He1, Chaoyang Liu1, Xinmiao Liang1*, and Jiwen Feng1 |
1State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Center for Magnetic Resonance, Key Laboratory of Magnetic Resonance in Biological Systems, Wuhan Institute of Physics and Mathematics, Innovation Academy for Precision Measurement Science and Technology, Chinese Academy of Sciences, Wuhan 430071, China
2University of Chinese Academy of Sciences, Beijing 100049, China
3College of Chemistry and Molecular Sciences, Hubei Key Laboratory of Electrochemical Power Sources, Wuhan University, Wuhan 430072, China
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| Cite this article: |
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Zhekai Zhang, Jiyu Tian, Junfei Chen et al 2021 Chin. Phys. Lett. 38 126801 |
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Abstract Lithium deposition on graphite electrode not only reduces fast-charging capability of lithium ion batteries but also causes safety trouble. Here, a low-field $^{7}$Li dynamic nuclear polarization (DNP) is used to probe Li plating on the surfaces of three types of carbon electrodes: hard carbon, soft carbon and graphite. Owing to the strong Fermi contact interaction between $^{7}$Li and conduction electrons, the $^{7}$Li nuclear-magnetic-resonance (NMR) signal of Li metal deposited on electrode surface could be selectively enhanced by DNP. It is suggested that low-field $^{7}$Li DNP spectroscopy is a sensitive tool for investigating Li deposition on electrodes during charging/discharging processes.
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Received: 11 October 2021
Published: 25 November 2021
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| PACS: |
82.47.Aa
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(Lithium-ion batteries)
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81.15.Pq
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(Electrodeposition, electroplating)
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76.70.Fz
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(Double nuclear magnetic resonance (DNMR), dynamical nuclear polarization)
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| Fund: Supported by the National Key Research and Development Program of China (Grant No. 2018YFC0115000), the National Natural Science Foundation of China (Grant No. 21603267), and the Chinese Academy of Sciences (Grant No. YZ201677 and YZ201551). |
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