Theoretical Analysis of Rydberg and Autoionizing State Spectra of Antimony
Shuang-Fei Lv1 , Ruohong Li2** , Feng-Dong Jia1** , Xiao-Kang Li1 , Jens Lassen2 , Zhi-Ping Zhong1
1 School of Physical Sciences, University of Chinese Academy of Sciences, Beijing 1000492 TRIUMF, Wesbrook Mall 4004, Vancouver, Canada
Abstract ：We calculate the Rydberg and autoionization Rydberg spectra of antimony (Sb) from first principles by relativistic multichannel theory within the framework of multichannel quantum defect theory. Our calculation can be used to classify and assign the atomic states described in recently reported three Rydberg series and four autoionizing states. The perturbation effects on line intensity, variation and line profile are discussed. Assignments of the perturber states and autoionizing states are presented.
收稿日期: 2017-03-07
出版日期: 2017-06-23
:
31.15.vj
(Electron correlation calculations for atoms and ions: excited states)
31.15.am
(Relativistic configuration interaction (CI) and many-body perturbation calculations)
32.80.Ee
(Rydberg states)
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2017, Vol. 34 
