Low-Temperature Solid State Synthesis and Characterization of Superconducting Vanadium Nitride
Liang-Biao Wang1** , Zheng-Song Lou1 , Ke-Yan Bao2** , Wei-Qiao Liu1 , Quan-Fa Zhou1**
1 School of Chemistry and Environment Engineering, Jiangsu University of Technology, Changzhou 2130012 College of Chemistry and Pharmcy Engineering, Nanyang Normal University, Nanyang 473061
Abstract ：Superconducting vanadium nitride (VN) is successfully synthesized by a solid-state reaction of vanadium pentoxide, sodium amide and sulfur in an autoclave at a relatively low temperature (240–400$^{\circ}\!$C). The obtained samples are characterized by x-ray diffraction, x-ray photoelectron spectroscopy and transmission electron microscopy. The result of the magnetization of the obtained VN product as a function of temperature indicates that the onset superconducting transition temperature is about 8.4 K. Furthermore, the possible reaction mechanism is also discussed.
收稿日期: 2016-11-12
出版日期: 2017-01-25
:
81.16.Be
(Chemical synthesis methods)
77.84.Bw
(Elements, oxides, nitrides, borides, carbides, chalcogenides, etc.)
87.64.Bx
(Electron, neutron and x-ray diffraction and scattering)
[1] Shy Y M, Toth, L E and Somasundaram R 1973 J. Appl. Phys. 44 5539 [2] Alexander A M and Hargreaves J S J 2010 Chem. Soc. Rev. 39 4388 [3] Wang L B, Zhu Y C, Shi L, Si L L, Li Q W and Qian Y T 2012 J. Nanosci. Nanotechnol. 12 7329 [4] Choi D, Blomgren G E and Kumta P N 2006 Adv. Mater. 18 1178 [5] Oyama S T 1992 Catal. Today 15 179 [6] Sun Q and Fu Z W 2008 Electrochim. Acta 54 403 [7] Gray K E, Kampwirth R T, Capone D W, Vaglio R and Zasadzinski J 1988 Phys. Rev. B 38 2333 [8] Koscielska B, Winiarski A and Jurga W 2010 J. Non-Cryst. Solids 356 1998 [9] Toth L E 1971 Transition Metal Carbides and Nitrides (New York: Academic Press) [10] Tripathy P K, Sehra J C and Kulkarni A V 2001 J. Mater. Chem. 11 691 [11] Chu X and Barnett S A 1996 J. Vac. Sci. Technol. A: Vac. Surf. Films 14 3124 [12] Dekker J P, Vanderput P J, Vering H J and Schoonman J 1994 J. Mater. Chem. 4 689 [13] Li Y G, Gao L, Li J G and Yan D S 2004 J. Am. Ceram. Soc. 85 1294 [14] Herle P S, Hegde M S, Vasathacharya N Y and Philip S 1997 J. Solid State Chem. 134 120 [15] Dai Z N, Miyashita A, Yamamoto S, Narumi K and Naramoto H 1999 Thin Solid Films 347 117 [16] Parkin I P 1996 Chem. Soc. Rev. 25 199 [17] Vaidhyanathan B, Agrawal D K and Roy R 2000 J. Mater. Res. 15 974 [18] Cai P J, Yang Z H, Wang C Y, Xia P and Qian Y T 2006 Mater. Lett. 60 410 [19] Wang L B, Li Q W, Zhu Y C and Qian Y T 2012 Int. J. Refract. Met. Hard Mter. 31 288 [20] Roldan M A, López-Flores V, Alcala M D, Ortega A and Real C 2010 J. Eur. Ceram. Soc. 30 2099 [21] Vaidhyanathan B and Rao K J 1997 Chem. Mater. 9 1196 [22] Houmes J D and Loye H C 1997 J. Solid State Chem. 130 266 [23] Zhao H Z, Lei M, Yang X A, Jian J K and Chen X L 2005 J. Am. Chem. Soc. 127 15722 [24] Hanumantha P J, Datta M K, Kadakia K S, Hong D H, Chung S J, Tam M C, Poston J A, Manivannan A and Kumta P N 2013 J. Electrochem. Soc. 160 A2195 [25] Ningthoujam R S and Gajbhiye N S 2015 Prog. Mater. Sci. 70 50 [26] Ahmad R, Hussain T, Khan I A and Rawat R S 2014 Chin. Phys. B 23 065204 [27] Hussain T, Ahmad R, Khalid N, Umar Z A and Hussain A 2013 Chin. Phys. B 22 055204 [28] Baba Y, Sasaki T A and Takano I 1988 J. Vac. Sci. Technol. A: Vac. Surf. Films 6 2945 [29] Cotton F A, Wilkinson G, Murillo C A and Bochmann M 1999 Advanced Inorganic Chemistry (New York: John Wiley & Sons) p 316
[1]
.
[2]
.
[3]
.
[4]
.
[5]
.
[6]
.
[7]
.
[8]
.
[9]
TAO Jun;LU Yong-Hua;ZHENG Rong-Sheng;LIN Kai-Qun;XIE Zhi-Guo;LUO Zhao-Feng;LI Sheng-Li;WANG Pei;MING Hai. Effect of Aspect Ratio Distribution on Localized Surface Plasmon Resonance Extinction Spectrum of Gold Nanorods
[10]
YAN Jun-Feng;ZHAO Li-Li;ZHANG Zhi-Yong. Optimization of (002)-Oriented ZnO Film Synthesis in Sol-Gel Process and Film Photoluminescence Property
[11]
FU Xiao-Nan;LI Xin-Jian. Enhanced Field Emission of Composite Au Nanostructured Network n Si Nanoporous Pillar Array
[12]
XUE De-Sheng;GONG Yu;LIU Wen-Jing;SI Ming-Su;LIU Zai-Wen. Photoluminescence Property of Co3 O4 Nanowires
[13]
SUN Guang;LIU Zhong-Yuan;HE Ju-Long;YU Dong-Li;TIAN Yong-Jun. Chemical Synthesis of C3 N and BC2 N Compounds
[14]
FU Xiao-Nan;LI Xin-Jian. Enhanced Field Emission from Well-Patterned Silicon Nanoporous Pillar Arrays
[15]
LI Meng-Ke;LU Mei;KONG Ling-Bin;WANG Cheng-Wei;GUO Xin-Yong;LI Hu-Lin. Photoluminescence Properties of Silicon Nanowires and Carbon Nanotube-Silicon Nanowire Composite Arrays
2017, Vol. 34 
