Third-Order Nonlinear Optical Response near the Plasmon Resonance Band of Cu$_{2-x}$Se Nanocrystals
Lan-Qing Zhou1,2 , Yan-Bang Zhang3 , Teng-Fei Yan2 , Ying Li2 , Guo-Zhi Jia3 , Huai-Zhe Xu1 , Xin-Hui Zhang2,4**
1 State Key Laboratory of Software Development Environment and Department of Physics, Beihang University, Beijing 1001912 State Key Laboratory of Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Science, P. O. Box 912, Beijing 1000833 School of Science, Tianjin Chengjian University, Tianjin 3003844 College of Materials Science and Opto-electronic Technology, University of Chinese Academy of Sciences, Beijing 100049
Abstract ：The third-order nonlinear optical properties of water-soluble Cu$_{2-x}$Se nanocrystals are studied in the near infrared range of 700–980 nm using a femtosecond pulsed laser by the $Z$-scan technique. It is observed that the nonlinear optical response of Cu$_{2-x}$Se nanocrystals is sensitively dependent on the excitation wavelength and exhibits the enhanced nonlinearity compared with other selenides such as ZnSe and CdSe. The W-shaped $Z$-scan trace, a mixture of the reversed saturated absorption and saturated absorption, is observed near the plasmon resonance band of Cu$_{2-x}$Se nanocrystals, which is attributed to the state-filling of free carriers generated by copper vacancies (self-doping effect) of Cu$_{2-x}$Se nanocrystals as well as the hot carrier thermal effect upon intense femtosecond laser excitation. The large nonlinear optical response and tunable plasmonic band make Cu$_{2-x}$Se nanocrystals promising materials for applications in ultra-fast all-optical switching devices as well as nonlinear nanosensors.
收稿日期: 2016-10-08
出版日期: 2016-12-29
:
42.65.An
(Optical susceptibility, hyperpolarizability)
42.70.Nq
(Other nonlinear optical materials; photorefractive and semiconductor materials)
78.20.Ci
(Optical constants (including refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity))
引用本文:
. [J]. 中国物理快报, 2017, 34(1): 14205-014205.
链接本文:
https://cpl.iphy.ac.cn/CN/10.1088/0256-307X/34/1/014205
或
https://cpl.iphy.ac.cn/CN/Y2017/V34/I1/14205
[1] Alivisatos A P 1996 Science 271 933 [2] Alivisatos A P 1996 J. Phys. Chem. 100 13226 [3] Cao J C 2003 Phys. Rev. Lett. 91 237401 [4] Cotter D, Burt M G and Manning R J 1992 Phys. Rev. Lett. 68 1200 [5] Jia W, Douglas E P, Guo F and Sun W 2004 Appl. Phys. Lett. 85 6326 [6] Anand B, Molli M, Aditha S, Rattan T M, Sai S S S and Kamisetti V 2013 Opt. Commun. 304 75 [7] Yang W X, Chen A X, Huang Z and Lee R K 2015 Opt. Express 23 13032 [8] Tripathi L N, Praveena M and Basu J K 2013 Plasmonics 8 657 [9] Zhou X, Wenger J, Viscomi F, Cunff L L and Beal J 2015 Nano Lett. 15 7458 [10] Potrick K and Huisken F 2015 Phys. Rev. B 91 125306 [11] Kulakovich O, Strekal N, Yaroshevich, Maskevich S and Gaponenko S 2002 Nano Lett. 2 1449 [12] Achermann M J 2010 J. Phys. Chem. Lett. 1 2837 [13] Pelayo G D A F, Lasanta T, Bernechea M and Konstantatos G 2015 Small 11 2636 [14] Song M, Wu B, Chen G, Liu Y, Ci X, Wu E and Zeng H 2014 J. Phys. Chem. C 118 8514 [15] Yang W X 2015 Opt. Lett. 40 4903 [16] Terzis A F, Kosionis S G, Boviatsis J and Paspalakis E 2016 J. Mod. Opt. 63 451 [17] Schindel D and Singh M R 2015 J. Phys.: Condens. Matter 27 345301 [18] Sadeghi S M, Wing W J and Gutha R R 2015 Phys. Rev. A 92 023808 [19] Paspalakis E, Evangelou S, Kosionis S G and Terzis A F 2014 J. Appl. Phys. 115 083106 [20] Carreño F, Antón M A, Melle S, Calderón O G and Cabrera-Granado E 2014 J. Appl. Phys. 115 064304 [21] Li J B, Kim N C, Cheng M T, Zhou L and Hao Z H 2012 Opt. Express 20 1856 [22] Gorbachev V V and Putilin I M 1973 Phys. Status Solidi A 16 553 [23] Choi J, Kang N, Yang H Y, Kim H J and Son S U 2010 Chem. Mater. 22 3586 [24] Zhu J B, Li Q Y, Bai L F, Sun Y F, Zhou M and Xie Y 2012 Chem. Eur. J. 18 13213 [25] Klimov V I and Karavanskii V A 1996 Phys. Rev. B 54 8087 [26] Kumar P and Singh K 2011 Struct. Chem. 22 103 [27] Scotognella F, Valle G D, Kandada A R S and Dorfs D 2011 Nano Lett. 11 4711 [28] Scotognella F, Valle G D, Kandada A R S, Zavelani-Rossi M and Longhi S 2013 Eur. Phys. J. B 86 1 [29] Valle G D, Scotognella F, Kandada A R S, Zavelani-Rossi M and Li H 2013 J. Phys. Chem. Lett. 4 3337 [30] Dorfs D, Haertling T, Miszta K, Bigall N C and Kim M R 2011 J. Am. Chem. Soc. 133 11175 [31] Zhao Y X, Pan H C, Lou Y B, Qiu X F, Zhu J J and Burda C 2009 J. Am. Chem. Soc. 131 4253 [32] Bussian D A, Crooker S A, Yin M, Brynda M and Efros A L 2009 Nat. Mater. 8 35 [33] Guri V S, Prokopenko V B, Alexeenko A A, Wang S and Prokoshin P V 2001 Mater. Sci. Eng. C 15 93 [34] Yumashev K V, Gurin V S, Prokoshin P V, Prokopenko V B and Alexeenko A A 2001 Phys. Status Solidi B 224 815 [35] Gurin V S, Prokopenko V B, Alexeenko A A, Wang S X, Yumashev K V and Prokoshin P V 2001 Int. J. Inorg. Mater. 3 493 [36] Gurin V S, Alexeenko A A, Zolotovskaya S A and Yumashev K V 2006 Mater. Sci. Eng. C 26 952 [37] Gerdova I and Hache A 2005 Opt. Commun. 246 205 [38] Jiao Y, Yu D B, Wang Z R and Sun X Q 2007 Mater. Lett. 61 1541 [39] Said A A, Sheik-Bahae M, Hagan D J, Wei T H and Wang J 1992 J. Opt. Soc. Am. B 9 405 [40] Jia G Z, Lou W K, Cheng F, Wang X L and Yao J H 2015 Nano Res. 8 1443 [41] Jia G Z, Wang P, Wu Z G, Li Q and Zhang Y B 2015 AIP Adv. 5 087176 [42] Kriegel I, Jiang C Y, Rodríguez-Fernandez J, Schaller R D and Talapin D V 2012 J. Am. Chem. Soc. 134 1583 [43] Statkutė G, Mikulskas I, Tomašiūnas R and Jagminas A 2009 J. Appl. Phys. 105 113519 [44] Luther J M, Jain P K, Ewers T and Alivisatos A P 2011 Nat. Mater. 10 361 [45] Sheik-Bahae M, Said A A, Wei T H, Hagan D J and van Stryland E W 1990 IEEE J. Quantum Electron. 26 760 [46] Sheik-Bahae M, Hagan D J and van Stryland E W 1990 Phys. Rev. Lett. 65 96 [47] Hutchings D C and van Stryland E W 1992 J. Opt. Soc. Am. B 9 2065 [48] Sheik-bahae M, Said A A and van Stryland E W 1989 Opt. Lett. 14 955 [49] Unnikrishnan K P, Nampoori V P N, Ramakrishnan V, Umadevi M and Vallabhan C P G 2003 J. Phys. D 36 1242 [50] Nan F, Zhang Y F, Li X G, Zhang X T, Li H and Zhang X H 2015 Nano Lett. 15 2705 [51] Sheik-Bahae M, Hutchings D C, Hagan D J and van Stryland E W 1991 IEEE J. Quantum Electron. 27 1296 [52] Cotter D, Burt M G and Manning R 1992 Phys. Rev. Lett. 68 1200 [53] Yu B H, Zhang D L, Li Y B and Tang Q B 2013 Chin. Phys. B 22 014212 [54] Fan G H, Qu S L, Guo Z Y and Li Z G 2012 Chin. Phys. B 21 047804
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2017, Vol. 34 
