Abstract:The crystal structures and magnetic properties of novel EuTrGa3?r (T=Pd, Ir, Rh) intermetallic compounds are investigated by using powder x-ray diffraction and magnetic measurements. EuTrGa3?r crystallizes in orthorhombic structure with space group of Cmcm and Z=4. There are four kinds of nonequivalent 4c crystal positions in EuTrGa3?r unit cell, which are occupied by 4Eu, 4GaI, 4(GaII, T) and 4GaIII, respectively. EuTrGa3?r exhibits the complex magnetic states in low-temperature regime, with the three-, two- and one-antiferromagnetic transitions occurring for T=Ir, T=Rh and T=Pd, respectively. It might be due to the Kondo effect: a localized antiferromagnetic interaction of the isolated impurity spins with the surrounding conduction electrons at low-temperature regime.
[1] Ohno H 1998 Science281 951 [2] Roy V A L, Djurisic A B, Liu H, Zhang X X, Leung Y H, Xie M H, Gao J, Lui H F and Surya C 2004 Appl. Phys. Lett.84 756 [3] Ciatto G, Di Trolio A, Fonda E, Alippi P, Testa A M and Bonapasta A A 2011 Phys. Rev. Lett.107 127206 [4] Xu Q Y, Hartmann L, Zhou S Q, Mcklich A, Helm M, Biehne G, Hochmuth H, Lorenz M, Grundmann M and Schmidt H 2008 Phys. Rev. Lett.101 076601 [5] Pereira L M C, Wahl U, Decoster S, Correia J G, Amorim L M, da Silva M R, Araujo J P and Vantomme A 2011 Phys. Rev. B 84 125204 [6] Khajetoorians A A, Chilian B, Wiebe J, Schuwalow S, Lechermann F and Wiesendanger R 2010 Nature467 1084 [7] Grin Y, Ellner M, Hiebl K, Baumgartner B and Rogl P 1995 J. Alloys Compd.221 125 [8] Nuspl G, Polborn K, Evers J, Landrum G A and Hoffmann R 1996 Inorg. Chem.35 6922 [9] Demooij D B and Buschow K H J 1985 J. Less Common Met.109 117 [10] Villars P, Calvert L D and Pearson W B 1991 Pearson's Handbook of Crystallographic Date for Intermetallic Phases (Materials park: American Society for Metals) [11] Markiv V Y, Belyavina N N and Shevchenko I P 1998 Izv Akad Nauk SSSR Met.3 119 [12] Guo Y Q, Grin Y, Schnelle W and Li W 2007 J. Appl. Phys.101 053505 [13] Rietveld H M 1969 J. Appl. Crystallogr.2 65 [14] Hill R J and Howard C J 1987 J. Appl. Crystallogr.20 467 [15] Nereson N G, Olsen C E and Arnold G P 1964 Phys. Rev. A 135 A176 [16] Nakamura A, Hiranaka Y C, Hedo M, Nakama T, Miura Y, Tsutsumi H, Mori A, Ishida K, Mitamura K, Hirose Y, Sugiyama K, Honda F, Settai R, Takeuchi T, Hagiwara M, Matsuda T D, Yamamoto E, Haga Y, Matsubayashi K, Uwatoko Y, Hatima H and ōuki Y 2013 J. Phys. Soc. Jpn.82 104703 [17] Bobev S, Bauer E D, Thompson J D and Sarrao J L 2004 J. Magn. Magn. Mater.277 236 [18] Haruo N, Saori N, Nonoka H, Mamoru Y, Yusuke H, Yoshichika ō and Hisatomo H 2014 JPS Conf. Proc.3 011015