Synthesis and Growth Mechanism: A Novel Fishing Rod-Shaped GaN Nanorods
ZHANG Shi-Ying1,2, XIU Xiang-Qian1**, HUA Xue-Mei1, XIE Zi-Li1, LIU Bin1, CHEN Peng1, HAN Ping1, LU Hai1, ZHANG Rong1, ZHENG You-Dou1
1Key Laboratory of Advanced Photonic and Electronic Materials, School of Electronic Science and Engineering, Nanjing University, Nanjing 210093 2College of Optoelectronics Engineering, Zaozhuang University, Zaozhuang 277160
Abstract:A novel fishing rod-shaped GaN nanorod is successfully fabricated through a new method by using the two-step growth technology. This growth method is applicable to continuous synthesis and is able to produce a large number of single-crystalline GaN nanorods with a relatively high purity and at a low cost. X-ray diffraction, scanning electron microscopy and high-resolution transmission electron microscopy are used to characterize the as-synthesized nanorods. The results show that most of the nanorods consist of a main rod and a top curved thread. It is single-crystal GaN with hexagonal wurtzite structure. The representative photoluminescence spectrum at room temperature exhibits a strong UV light emission band centered at 370.8 nm. Furthermore, a possible two-stage growth mechanism of the fishing rod-shaped GaN nanorod is also briefly discussed.