Stereodynamics and Rovibrational Effect for H+NH3 →H2 +NH2 Reaction
LI Hao, LIU Xin-Guo, ZHANG Qing-Gang
College of Physics and Electronics, Shandong Normal University, Jinan 250014
Stereodynamics and Rovibrational Effect for H+NH3 →H2 +NH2 Reaction
LI Hao;LIU Xin-Guo;ZHANG Qing-Gang
College of Physics and Electronics, Shandong Normal University, Jinan 250014
关键词 ：
31.15.Qg ,
31.70.Hq ,
34.50.Dy
Abstract ： We employ the semirigid vibrating rotor target (SVRT) model to study the influence of rotational and vibrational excitation of the reagent on reactivity for the reaction H+NH3 . The excitation of the2 stretching vibration of the SVRT model gives significant enhancement of reaction probability. Detailed study of the influence of initial rotational states on reaction probability shows strong steric effect. The steric effect of polyatomic reactions, treated by the SVRT model, is more complex and richer than theoretical calculations involving linear molecular models.
Key words ：
31.15.Qg
31.70.Hq
34.50.Dy
出版日期: 2005-05-01
引用本文:
LI Hao;LIU Xin-Guo;ZHANG Qing-Gang. Stereodynamics and Rovibrational Effect for H+NH3 →H2 +NH2 Reaction[J]. 中国物理快报, 2005, 22(5): 1093-1096.
3 →H2 +NH2 Reaction. Chin. Phys. Lett., 2005, 22(5): 1093-1096.
链接本文:
https://cpl.iphy.ac.cn/CN/
或
https://cpl.iphy.ac.cn/CN/Y2005/V22/I5/1093
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