A Statistical Theory for Hydrogen Bonding Networks: One Component Case
WANG Hai-Jun1, BA Xin-Wu1, ZHAO Min1, LI Ze-Sheng2
1Department of Chemistry, Hebei University, Baoding 071002
2Institute of Theoretical Chemistry and State Key Laboratory of Theoretical and Computational Chemistry, Jilin University, Changchun 130023
A Statistical Theory for Hydrogen Bonding Networks: One Component Case
WANG Hai-Jun1;BA Xin-Wu1;ZHAO Min1;LI Ze-Sheng2
1Department of Chemistry, Hebei University, Baoding 071002
2Institute of Theoretical Chemistry and State Key Laboratory of Theoretical and Computational Chemistry, Jilin University, Changchun 130023
Abstract： The theory of reversible gelation is shown to be applicable to the hydrogen bonding system by analyzing their similarities in statistical viewpoint. The size distribution of hydrogen bonding clusters, the gelation condition and the generalized scaling law can be obtained directly. These results show that such a system can undergo phase transition process. Furthermore, a relationship between Gibbs free energy of forming hydrogen bond and conversions of groups is given. As an example, the chemical shift of OH groups is considered.
WANG Hai-Jun;BA Xin-Wu;ZHAO Min;LI Ze-Sheng. A Statistical Theory for Hydrogen Bonding Networks: One Component Case[J]. 中国物理快报, 2000, 17(1): 16-18.
WANG Hai-Jun, BA Xin-Wu, ZHAO Min, LI Ze-Sheng. A Statistical Theory for Hydrogen Bonding Networks: One Component Case. Chin. Phys. Lett., 2000, 17(1): 16-18.
2000, Vol. 17 
