A series of GaAs1-ySby epilayers are grown on GaAs substrates under different growth conditions. Different antimony compositions of samples with beryllium doping are obtained. A non-equilibrium thermodynamics model is used to calibrate and fit the Sb composition. Activation energy of 0.37eV for the dissociation process of Sb4 molecules is obtained. Carrier mobility and concentration of samples are influenced by the Sb composition. Quasi-qualitative analysis of mobility is used to explain the relations among Sb composition, carrier mobility and concentration. High resolution x-ray diffraction (HRXRD) rocking curves and Hall effects measurements are used to determine the crystal quality, carrier mobility and concentration.
A series of GaAs1-ySby epilayers are grown on GaAs substrates under different growth conditions. Different antimony compositions of samples with beryllium doping are obtained. A non-equilibrium thermodynamics model is used to calibrate and fit the Sb composition. Activation energy of 0.37eV for the dissociation process of Sb4 molecules is obtained. Carrier mobility and concentration of samples are influenced by the Sb composition. Quasi-qualitative analysis of mobility is used to explain the relations among Sb composition, carrier mobility and concentration. High resolution x-ray diffraction (HRXRD) rocking curves and Hall effects measurements are used to determine the crystal quality, carrier mobility and concentration.
[1] Peter M et al 1999 Appl. Phys. Lett. 74 410 [2] Dvorak M W et al 2001 IEEE Electron. Devices Lett. 22 361 [3] Tohruoka et al 2001 Appl. Phys. Lett. 78 483 [4] Dvorak M W et al 2000 J. Vac. Sci. Technol. A 18 761 [5] Renard C et al 2005 J. Cryst. Growth 278 193 [6] Genty F et al 1999 J. Cryst. Growth 201-2021024 [7] Seki H and Koukitu A 1986 J. Cryst. Growth 78342 [8] Yu Egorov A et al 1998 J. Cryst. Growth 188 69 [9] Nomura T et al 1991 J. Cryst. Growth 111 61 [10] Liang B W and Tu C W 1993 J. Appl. Phys. 74255 [11] Hao Z B et al 2001 J. Cryst. Growth 224 224 [12] Wu S D et al 2004 J. Cryst. Growth 270 359 [13] Oka T et al 2001 Appl. Phys. Lett. 78 483 [14] Oda Y et al 2005 Appl. Phys. Lett. 87 023503 [15] Tian Y and Wang H 2006 J. Cryst. Growth 270359 [16] Andr\'{e R, Wey S and Tu C W 2002 J. Cryst. Growth 235 65