Photoluminescence and Electroluminescence of Poly p-Phenyl Phenol Prepared by Enzymatic Catalyzed Polymerization
MA Yuguang, TANG Jianguo, MA Lin1, LIU Shiyong, SHEN Jiacong2
The National Laboratory of Integrated Optic Electronics,
1The National Laboratory of Enzyme Engineering,
2The Key Laboratory for Molecular Spectra and Structure, Jilin University, Changchun 130023
Photoluminescence and Electroluminescence of Poly p-Phenyl Phenol Prepared by Enzymatic Catalyzed Polymerization
MA Yuguang;TANG Jianguo;MA Lin1;LIU Shiyong;SHEN Jiacong2
The National Laboratory of Integrated Optic Electronics,
1The National Laboratory of Enzyme Engineering,
2The Key Laboratory for Molecular Spectra and Structure, Jilin University, Changchun 130023
Abstract: The photoluminescence (PL) peak of poly p-phenyl phenol (PPP) is at about 370-420nm excited by the light at 350nm. The absorption band edges and photon emitting peaks of the polymer are found the conjugated lengths dependent on molecular weight of polymer. In the transient luminescence measurement the lifetime of PL decay is determined to be 2.0ns which is supposed an evidence of polaron excitation recombination. The electroluminescence is observed with aluminum/PPP/indium- tinoxide cell.