Influence of Residual Phases on the Behaviour of Gradual Spin Transition Complexes
SHI Hai-Rong, YU Zhi, HUANG Hong-Bo, XIA Yuan-Fu, YOU Xiao-Zeng
National Laboratory of Solid State Microstructure, Department
of Physics, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093
Influence of Residual Phases on the Behaviour of Gradual Spin Transition Complexes
SHI Hai-Rong;YU Zhi;HUANG Hong-Bo;XIA Yuan-Fu;YOU Xiao-Zeng
National Laboratory of Solid State Microstructure, Department
of Physics, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093
Abstract： In order to interpret the large shift between the observed high spin fraction and the so-called molar high spin fraction in the Mössbauer study on gradual spin transition complexes, numerically we reveal that the effects from residual phases in the substance should be considered in the correction by Debye-Waller factors. This result shows that similar Debye-Waller factors in high and low spin states agree well with the conclusion of experimental investigations for such gradual spin transition complexes.
(Statistical mechanics of lattice vibrations and displacive phase transitions)
引用本文:
SHI Hai-Rong;YU Zhi;HUANG Hong-Bo;XIA Yuan-Fu;YOU Xiao-Zeng. Influence of Residual Phases on the Behaviour of Gradual Spin Transition Complexes[J]. 中国物理快报, 2001, 18(4): 611-613.
SHI Hai-Rong, YU Zhi, HUANG Hong-Bo, XIA Yuan-Fu, YOU Xiao-Zeng. Influence of Residual Phases on the Behaviour of Gradual Spin Transition Complexes. Chin. Phys. Lett., 2001, 18(4): 611-613.
2001, Vol. 18 
