On the Scaling Law for Af Type Free Radical Homopolymerization
WANG Hai-jun1, BA Xin-wu1, ZHAO Min1, LI Ze-sheng2
1Department of Chemistry, Hebei University, Baoding 071002
2Institute of Theoretical Chemistry & State Key Laboratory of Theoretical and Computational Chemistry, Jilin University, Changchun 130023
On the Scaling Law for Af Type Free Radical Homopolymerization
WANG Hai-jun1;BA Xin-wu1;ZHAO Min1;LI Ze-sheng2
1Department of Chemistry, Hebei University, Baoding 071002
2Institute of Theoretical Chemistry & State Key Laboratory of Theoretical and Computational Chemistry, Jilin University, Changchun 130023
Abstract： From the equilibrium number fraction distribution for Af type free radical homopolymerization, the asymptotic distribution and polymer moments near the gel point are deduced. As a direct result of scaling transformation, ageneralized scaling law which characterizes the sol-gel transition is obtained. This reveals that the curing of this type is in essence a phase transition process.
WANG Hai-jun;BA Xin-wu;ZHAO Min;LI Ze-sheng. On the Scaling Law for Af Type Free Radical Homopolymerization[J]. 中国物理快报, 1999, 16(4): 301-303.
WANG Hai-jun, BA Xin-wu, ZHAO Min, LI Ze-sheng. On the Scaling Law for Af Type Free Radical Homopolymerization. Chin. Phys. Lett., 1999, 16(4): 301-303.
1999, Vol. 16 
