Polaronic Tunnelling in Organic Triblock Copolymers
LIU De-Sheng1,2,3 , ZHANG Da-Cheng1,3 , XIE Shi-Jie1,3 , MEI Liang-Mo1,3
1 School of Physics and Microelectronics, Shandong University, Jinan 250100
2 Department of Physics, Jining Normal University, Jining 272025
3 National Key Laboratory of Crystal Materials, Shandong University, Jinan 250100
Polaronic Tunnelling in Organic Triblock Copolymers
LIU De-Sheng1,2,3 ;ZHANG Da-Cheng1,3 ;XIE Shi-Jie1,3 ;MEI Liang-Mo1,3
1 School of Physics and Microelectronics, Shandong University, Jinan 250100
2 Department of Physics, Jining Normal University, Jining 272025
3 National Key Laboratory of Crystal Materials, Shandong University, Jinan 250100
关键词 :
66.35.+a ,
72.80.Le ,
85.35.Be
Abstract : Polaron tunnelling is studied in xPA/nPPP/xPA (PA for polyacetylene and PPP poly (p-phenylene)) triblock copolymer, which has a well--barrier--well structure. An extended tight-binding Hamiltonian including external electric field is adopted. Without electric field, the injected electrons would not extend over the whole copolymer chain but instead be confined in the segments of PA. This is different from the behaviour of the traditional semiconductors. It is found that the polaron can transfer to the potential barrier-PPP segment when the applied electric field reaches a certain value. The critical polaron tunnelling electric fields depend upon the lengths of PPP segments.
Key words :
66.35.+a
72.80.Le
85.35.Be
出版日期: 2005-01-01
:
66.35.+a
(Quantum tunneling of defects)
72.80.Le
(Polymers; organic compounds (including organic semiconductors))
85.35.Be
(Quantum well devices (quantum dots, quantum wires, etc.))
引用本文:
LIU De-Sheng;;ZHANG Da-Cheng;XIE Shi-Jie;MEI Liang-Mo;. Polaronic Tunnelling in Organic Triblock Copolymers[J]. 中国物理快报, 2005, 22(1): 178-181.
LIU De-Sheng, , ZHANG Da-Cheng, XIE Shi-Jie, MEI Liang-Mo,. Polaronic Tunnelling in Organic Triblock Copolymers. Chin. Phys. Lett., 2005, 22(1): 178-181.
链接本文:
https://cpl.iphy.ac.cn/CN/
或
https://cpl.iphy.ac.cn/CN/Y2005/V22/I1/178
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