1Department of Physics, Center for Atomic and Molecular Sciences, Tsinghua University, Beijing 100084
2Department of Physics, the Graduate School of Chinese Academy of Sciences, PO Box 3908, Beijing 100039
3Department of Physics, Capital Normal University, Beijing 100037
Theoretical Analysis of Ionic Autoionization Spectra of Lanthanum in the Energy Region of 90650-91500 cm-1
1Department of Physics, Center for Atomic and Molecular Sciences, Tsinghua University, Beijing 100084
2Department of Physics, the Graduate School of Chinese Academy of Sciences, PO Box 3908, Beijing 100039
3Department of Physics, Capital Normal University, Beijing 100037
Abstract: Eigenquantum defects μα and transformation matrix Uiα of La+ are calculated from the first principles by relativistic multichannel theory, and dipole matrix elements Dα are obtained by fitting the experimental spectra. With these parameters, ionic autoionization spectra of lanthanum via an intermediate state (Xe)5d6d1P1 of La+ in the energy region of 90650-91500cm-1 are calculated within the framework of multichannel quantum defect theory. Our calculated spectra are in general agreement with the experimental data.
ZHANG Xin-Feng;PENG Yong-Lun;ZHONG Zhi-Ping;QU Yi-Zhi;SUN Wei;XIA Dan;XUE Ping;XU Xiang-Yuan;. Theoretical Analysis of Ionic Autoionization Spectra of Lanthanum in the Energy Region of 90650-91500 cm-1[J]. 中国物理快报, 2003, 20(8): 1242-1243.
ZHANG Xin-Feng, PENG Yong-Lun, ZHONG Zhi-Ping, QU Yi-Zhi, SUN Wei, XIA Dan, XUE Ping, XU Xiang-Yuan,. Theoretical Analysis of Ionic Autoionization Spectra of Lanthanum in the Energy Region of 90650-91500 cm-1. Chin. Phys. Lett., 2003, 20(8): 1242-1243.