Effects of Yb 3+ in Er 3+/Yb 3+ Codoped Fluorophosphate Glasses
LIAO Mei-Song1, FANG Yong-Zheng1, Hu Li-li1, ZHANG Li-Yan2, XU Shi-Qing2
1Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 2018002College of Information Engineering, China Jiliang University, Hangzhou 310018
Effects of Yb 3+ in Er 3+/Yb 3+ Codoped Fluorophosphate Glasses
1Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 2018002College of Information Engineering, China Jiliang University, Hangzhou 310018
摘要For the Er3+/Yb3+ codoped fluorophosphate glasses, Judd--Ofelt theory is used to analyse the influence of YbF3 as not a sensitizer but an average component on the spectroscopic properties around 1530\,nm emission. The double roles of Yb3+, as a sensitizer and as an average component, are discussed. It is found that Yb3+ as an average component contributes to the increase of fluorescence lifetime, and Yb3+ as a sensitizer has the best sensitization when its concentration is 2.4mol%.
Abstract:For the Er3+/Yb3+ codoped fluorophosphate glasses, Judd--Ofelt theory is used to analyse the influence of YbF3 as not a sensitizer but an average component on the spectroscopic properties around 1530\,nm emission. The double roles of Yb3+, as a sensitizer and as an average component, are discussed. It is found that Yb3+ as an average component contributes to the increase of fluorescence lifetime, and Yb3+ as a sensitizer has the best sensitization when its concentration is 2.4mol%.
[1] Yang J H et al 2003 J. Opt. Soc. Am. B 20 810 [2] Nazabal V et al 2003 J. Non-Cryst. Solid 326/327 359 [3] Xu S Q et al 2003 J. Alloy. Compound. 361 313 [4] Yu C L et al 2005 Chin. Phys. Lett. 22 2926 [5] Liu Z P et al 2003 Opt. Mater. 21 789 [6] Zhang L Y et al 2005 Mater. Chem. Phys. 91 166 [7] Judd B R 1962 Phys. Rev. 127 750 [8] Ofelt G S 1962 J. Chem. Phys. 37 511 [9] Ivanova T Y et al 2002 J. Non-Cryst. Solid. 298 7 [10] Weber M J 1967 Phys. Rev. 157 262 [11] Tanabe S et al 1992 Phys. Rev. B 46 3305 [12] Karmakar B et al 2000 J. Am. Ceram. Soc. 83 1305 [13] Yasui I et al 1992 J. Non-Cryst. Solid. 140 130 [14] Dai S X et al 2006 J. Lumin. 117 39 [15] Weber M J 1973 Phys. Rev. B 8 54 [16] De la Rosa-Cruz E et al 2001 Optic. Mater. 18 321 [17] Yang J H et al 2004 J. Lumin. 106 9 [18] Pan J V et al 1970 Phys. Rev. B 2 4432 [19] Houde-Walter S N et al 2001 J. Non-Cryst. Solid. 286118 [20] Kumar G A et al 2003 J. Phys. Chem. Solid. 64 69 [21] Yan Y C et al 1995 J. Non-Cryst. Solid. 181 283