摘要Ca3Y2(BO3)4:Eu3+ phosphor is synthesized by high temperature solid-state reaction method, and the luminescence characteristics are investigated. The emission spectrum exhibits two strong red emissions at 613 and 621nm corresponding to the electric dipole 5D0--7F2 transition of Eu3+ under 365nm excitation, the reason is that Eu3+ substituting for Y3+ occupies the non-centrosymmetric position in the crystal structure of Ca3Y2(BO3)4. The excitation spectrum for 613nm indicates that the phosphor can be effectively excited by ultraviolet (UV) (254nm, 365nm and 400nm) and blue (470nm) light. The effect of Eu3+ concentration on the emission intensity of Ca3Y2(BO3)4:Eu3+ phosphor is measured, the result shows that the emission intensities increase with increasing Eu3+ concentration, then decrease. The CIE colour coordinates of Ca3Y2(BO3)4:Eu3+ phosphor is (0.639, 0.357) at 15mol% Eu3+.
Abstract：Ca3Y2(BO3)4:Eu3+ phosphor is synthesized by high temperature solid-state reaction method, and the luminescence characteristics are investigated. The emission spectrum exhibits two strong red emissions at 613 and 621nm corresponding to the electric dipole 5D0--7F2 transition of Eu3+ under 365nm excitation, the reason is that Eu3+ substituting for Y3+ occupies the non-centrosymmetric position in the crystal structure of Ca3Y2(BO3)4. The excitation spectrum for 613nm indicates that the phosphor can be effectively excited by ultraviolet (UV) (254nm, 365nm and 400nm) and blue (470nm) light. The effect of Eu3+ concentration on the emission intensity of Ca3Y2(BO3)4:Eu3+ phosphor is measured, the result shows that the emission intensities increase with increasing Eu3+ concentration, then decrease. The CIE colour coordinates of Ca3Y2(BO3)4:Eu3+ phosphor is (0.639, 0.357) at 15mol% Eu3+.
LI Pan-Lai;YANG Zhi-Ping;WANG Zhi-Jun;Guo Qing-Lin. Preparation and Luminescence Characteristics of Ca3Y2(BO3)4:Eu3+ Phosphor[J]. 中国物理快报, 2007, 24(10): 2977-2979.
LI Pan-Lai, YANG Zhi-Ping, WANG Zhi-Jun, Guo Qing-Lin. Preparation and Luminescence Characteristics of Ca3Y2(BO3)4:Eu3+ Phosphor. Chin. Phys. Lett., 2007, 24(10): 2977-2979.
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