Abstract: The kinetics and dynamics for the growth of hydrogen bonding clusters in the Aa-Dd system are considered. The explicit relations between conversions of proton-acceptors and proton-donors and Gibbs free energy are deduced, and then the sol-gel phase transition is predicted to take place and the generalized scaling laws satisfied by the k-th moment and k-th radius near the critical point are given. The conclusions obtained from which are consistent with the statistical descriptions on the system under investigation.
(Transition state theory and statistical theories of rate constants)
引用本文:
WANG Hai-Jun;HONG Xiao-Zhong;BA Xin-Wu. Statistics and Dynamics for the Aa-Dd Type Hydrogen Bonding System[J]. 中国物理快报, 2003, 20(7): 1158-1160.
WANG Hai-Jun, HONG Xiao-Zhong, BA Xin-Wu. Statistics and Dynamics for the Aa-Dd Type Hydrogen Bonding System. Chin. Phys. Lett., 2003, 20(7): 1158-1160.