Optical Parameters and Absorption of Azo Dye and Its Metal-Substituted Compound Thin Films
WEI Bin, WU Yi-Qun, GU Dong-Hong, GAN Fu-Xi
Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, PO Box 800-211, Shanghai 201800
Optical Parameters and Absorption of Azo Dye and Its Metal-Substituted Compound Thin Films
WEI Bin;WU Yi-Qun;GU Dong-Hong;GAN Fu-Xi
Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, PO Box 800-211, Shanghai 201800
关键词 :
78.20.Ci ,
78.66.Qn ,
42.70.Nq ,
42.70.Ln
Abstract : We determine the complex refractive indexes N(N = n-ik), dielectric constants ε(ε = ε1 - iε2 ), and absorption coefficients α of a new azo dye [2-(6-methyl-2-benzothiazolyazo)-5-diethylaminophenol(MBADP)]-doped polymer and its nickel- and zinc-substituted compounds(Ni-MBADP and Zn-MBADP) spin-coated thin films from an scanning ellipsometer in the wavelength 400-700 nm region. Metal chelation strongly (about one times) enhances the optical and dielectric parameters at the peaks and results in a large bathochromic shift (50-60 nm) of absorption band. Bathochromic shift of Ni-MBADP is about 10 nm larger than that of Zn-MBADP due to different spatial configurations formed in the metal-azo complexes.
Key words :
78.20.Ci
78.66.Qn
42.70.Nq
42.70.Ln
出版日期: 2003-09-01
:
78.20.Ci
(Optical constants (including refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity))
78.66.Qn
(Polymers; organic compounds)
42.70.Nq
(Other nonlinear optical materials; photorefractive and semiconductor materials)
42.70.Ln
(Holographic recording materials; optical storage media)
引用本文:
WEI Bin;WU Yi-Qun;GU Dong-Hong;GAN Fu-Xi. Optical Parameters and Absorption of Azo Dye and Its Metal-Substituted Compound Thin Films[J]. 中国物理快报, 2003, 20(9): 1596-1599.
WEI Bin, WU Yi-Qun, GU Dong-Hong, GAN Fu-Xi. Optical Parameters and Absorption of Azo Dye and Its Metal-Substituted Compound Thin Films. Chin. Phys. Lett., 2003, 20(9): 1596-1599.
链接本文:
https://cpl.iphy.ac.cn/CN/
或
https://cpl.iphy.ac.cn/CN/Y2003/V20/I9/1596
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