Local Structure Distortion and Quadrupole Splitting of Fe Ions in Bal+xNdl-xFeTiO6
LI Li-ping1, LI Guang-she2, SONG Xiao-yu1, MIA0 Ji-peng1, ZHOU Xian-feng1, SU Wen-hui1,3
1Department of Physics, Jilin University, Changchun 130023
2Electronic Materials Research Laboratory, Xian Jiaotong University, Xian 710049
3International Center for Material Physics, Chinese Academy of Sciences, Shenyang 110015
Local Structure Distortion and Quadrupole Splitting of Fe Ions in Bal+xNdl-xFeTiO6
LI Li-ping1;LI Guang-she2;SONG Xiao-yu1;MIA0 Ji-peng1;ZHOU Xian-feng1;SU Wen-hui1,3
1Department of Physics, Jilin University, Changchun 130023
2Electronic Materials Research Laboratory, Xian Jiaotong University, Xian 710049
3International Center for Material Physics, Chinese Academy of Sciences, Shenyang 110015
Abstract: A series of samples Bal+xNdl-xFeTiO6(x = 0.0-0.5) were prepared by solid state reactions and characterized by x-ray diffraction and Mössbauer spectroscopy. All samples crystallized in cubic structure. A random distribution of Fe and Ti ions at octahedral sites was shown. 57Fe Mössbauer spectra of the samples consisted of a quadrupole doublet. The quadrupole splittings obtained by fitting the experimental data were larger than 0.5mm/s, indicating local structure distortions in these cubic phases. The relationship between quadrupole splitting and dopant content x of Bal+xNdl-xFeTiO6is discussed.
(Other topics in structure of solids and liquids; crystallography)
引用本文:
LI Li-ping;LI Guang-she;SONG Xiao-yu;MIA0 Ji-peng;ZHOU Xian-feng;SU Wen-hui;. Local Structure Distortion and Quadrupole Splitting of Fe Ions in Bal+xNdl-xFeTiO6[J]. 中国物理快报, 1998, 15(12): 925-927.
LI Li-ping, LI Guang-she, SONG Xiao-yu, MIA0 Ji-peng, ZHOU Xian-feng, SU Wen-hui,. Local Structure Distortion and Quadrupole Splitting of Fe Ions in Bal+xNdl-xFeTiO6. Chin. Phys. Lett., 1998, 15(12): 925-927.