Quantum Engineering of Helical Charge Migration in HCCI
ChunMei Liu1 , Jörn Manz2,3,4* , Huihui Wang3,4 , and Yonggang Yang3,4*
1 Crystal Physics Research Center, College of Science, Nanjing University of Posts and Telecommunications, Nanjing 210023, China2 Institut für Chemie und Biochemie, Freie Universität Berlin, 14195 Berlin, Germany3 State Key Laboratory of Quantum Optics and Quantum Optics Devices, Institute of Laser Spectroscopy, Shanxi University, Taiyuan 030006, China4 Collaborative Innovation Center of Extreme Optics, Shanxi University, Taiyuan 030006, China
Abstract ：Electronic charge of molecules can move on time scales when the nuclei stand practically still, from few hundreds of attoseconds to few femtoseconds. This ultrafast process is called “charge migration”. A typical consequence is rapid change of electronic dipole, which points to the center of charge. Corresponding linear (one-dimensional, 1D) and planar (2D) dipolar motions have already been well documented. Here we construct the first case of charge migration which causes chiral 3D dipolar motion, specifically along a helix about oriented iodo-acetylene (HCCI). Quantum dynamics simulations show that this can be induced by well-designed laser pulses.
收稿日期: 2022-10-11
Editors' Suggestion
出版日期: 2022-11-22
:
34.50.Gb
(Electronic excitation and ionization of molecules)
82.53.-k
(Femtochemistry)
31.70.Hq
(Time-dependent phenomena: excitation and relaxation processes, and reaction rates)
32.80.Qk
(Coherent control of atomic interactions with photons)
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2022, Vol. 39 
