Synthesis of Polycrystalline Diamond Compact with Selenium: Discovery of a New Se–C Compound
Wen-Dan Wang1** , Ao Li1 , Guo-Heng Xu2 , Pei Wang3 , Yue-Gao Liu4 , Li-Ping Wang3**
1 School of Physical Science and Technology, Southwest Jiaotong University, Chengdu 6100312 Materials Research Center, Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 7300003 Academy for Advanced Interdisciplinary Studies, Southern University of Science and Technology (SUSTech), Shenzhen 5180554 CAS Key Laboratory for Experimental Study under Deep-Sea Extreme Conditions, Institute of Deep-Sea Science and Engineering, Chinese Academy of Sciences, Sanya 572000
Abstract ：Sintering of polycrystalline diamond with selenium was investigated under pressure of 6.5–10.5 GPa at a constant temperature of 1850 $^{\circ}\!$C. A new carbon-selenium compound with a most plausible chemical formula of SeC and a WC-type hexagonal structure (space group $P\bar{6}m2$) has been discovered in the recovered samples sintered at 10.5 GPa and 1850 $^{\circ}\!$C. Refined lattice parameters are as follows: $a = 2.9277(4)$ Å, $c = 2.8620(4)$ Å, $V = 21.245(4)$ Å$^{3}$. The diamond compacts hot-pressed at 10.5 GPa have excellent mechanical properties with a Vickers hardness of about 68 GPa at a loading force of 19.6 N. Diamond intergrowths observed in these samples may have benefited from the catalytic effects of Se/SeC on the nucleation and crystal growth of diamond.
收稿日期: 2020-02-20
出版日期: 2020-04-25
:
81.05.Uw
81.20.Ev
(Powder processing: powder metallurgy, compaction, sintering, mechanical alloying, and granulation)
61.66.Fn
(Inorganic compounds)
[1] Bundy F P, Hall H T, Strong H M and Wentorf Jun R H 1955 Nature 176 51 [2] Palyanov Y N, Kupriyanov I N, Khokhryakov A F and Ralchenko V G 2015 Handbook of Crystal Growth (Boston: Elsevier) chap 17 p 671 [3] Eversole W G 1960 US Patent No. 3030187 [4] Bovenkerk H P, Bundy F P, Hall H T, Strong H M and Wentorf R H 1959 Nature 184 1094 [5] Wakatsuki M 1966 Jpn. J. Appl. Phys. 5 337 [6] Bundy F P, Bovenkerk H P, Strong H M and Jr. R H W 1961 J. Chem. Phys. 35 383 [7] Kanda H, Akaishi M and Yamaoka S 1994 Appl. Phys. Lett. 65 784 [8] Fagan A J and Luth R W 2011 Contrib. Mineral. Petrol. 161 229 [9] Palyanov Y N, Kupriyanov I N, Borzdov Y M and Surovtsev N V 2015 Sci. Rep. 5 14789 [10] Palyanov Y N, Kupriyanov I N, Borzdov Y M, Khokhryakov A F and Surovtsev N V 2016 Cryst. Growth & Des. 16 3510 [11] Akaishi M, Kanda H and Yamaoka S 1993 Science 259 1592 [12] Palyanov Y N, Kupriyanov I N, Sokol A G, Khokhryakov A F and Borzdov Y M 2011 Cryst. Growth & Des. 11 2599 [13] Sato K and Katsura T 2001 J. Cryst. Growth 223 189 [14] Borzdov Y, Pal'yanov Y, Kupriyanov I, Gusev V, Khokhryakov A, Sokol A and Efremov A 2002 Diamond Relat. Mater. 11 1863 [15] Minoru A, Hisao K and Shinobu Y 1990 Jpn. J. Appl. Phys. 29 L1172 [16] Wang Y and Kanda H 1998 Diamond Relat. Mater. 7 57 [17] Pal'yanov Y N, Sokol A G, Borzdov Y M, Khokhryakov A F and Sobolev N V 1999 Nature 400 417 [18] Sokol A, Palyanov Y, Pal'yanova G and Tomilenko A 2004 Geochem. Int. 42 830 [19] Arima M, Nakayama K, Akaishi M, Yamaoka S and Kanda H 1993 Geology 21 968 [20] Akaishi M and Yamaoka S 2000 J. Cryst. Growth 209 999 [21] Sokol A G, Pal'yanov Y N, Pal'yanova G A, Khokhryakov A F and Borzdov Y M 2001 Diamond Relat. Mater. 10 2131 [22] Yamaoka S, Kumar M D S, Kanda H and Akaishi M 2002 Diamond Relat. Mater. 11 1496 [23] Dong J, Yao Z, Yao M, Li R, Hu K, Zhu L, Wang Y, Sun H, Sundqvist B, Yang K and Liu B 2020 Phys. Rev. Lett. 124 065701 [24] Chen M, Shu J, Xie X, Tan D and Mao H K 2018 Proc. Natl. Acad. Sci. USA 115 2676 [25] Akaishi M, Yamaoka S, Ueda F and Ohashi T 1996 Diamond Relat. Mater. 5 2 [26] Kovalenko T V and Ivakhnenko S A 2013 J. Superhard Mater. 35 131 [27] Palyanov Y N, Kupriyanov I N, Khokhryakov A F and Borzdov Y M 2017 CrystEngComm 19 4459 [28] Palyanov Y N, Borzdov Y M, Kupriyanov I N, Khokhryakov A F and Nechaev D V 2015 CrystEngComm 17 4928 [29] Wang J K, Li S S, Wang N, Liu H J, Su T C, Hu M H, Han F, Yu K P and Ma H A 2019 Chin. Phys. Lett. 36 046101 [30] Lv S J, Hong S M, Yuan C S and Hu Y 2009 Appl. Phys. Lett. 95 242105 [31] Lv S J, Luo J T, Su L, Hu Y, Yuan C S and Hong S M 2009 Acta Phys. Sin. 58 6852 (in Chinese) [32] Toby B 2001 J. Appl. Crystallogr. 34 210 [33] Powell B and Torrie B 1983 Acta Crystallogr. Sect. C: Cryst. Struct. Commun. 39 963 [34] Brazhkin V V, Popova S V and Voloshin R N 1999 Physica B 265 64 [35] Xu B and Tian Y 2015 J. Phys. Chem. C 119 5633 [36] Dub S, Lytvyn P, Strelchuk V, Nikolenko A, Stubrov Y, Petrusha I, Taniguchi T and Ivakhnenko S 2017 Crystals 7 369 [37] Wang W D, He D W, Tang M J, Li F J, Liu L and Bi Y 2012 Diamond Relat. Mater. 27 49 [38] Yu H, Li S and Hu E 1994 Diamond Relat. Mater. 3 222
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2020, Vol. 37 
