Chin. Phys. Lett.  2007, Vol. 24 Issue (7): 2028-2031    DOI:
Original Articles |
Liquid--Liquid Structure Transition in Metallic Melts: Experimental Evidence by Viscosity Measurement
WANG Yu-Qing;WU Yu-Qin;BIAN Xiu-Fang
Key Laboratory of Liquid Structure and Heredity of Materials (Ministry of Education), Shandong University, Jinan 250061
Cite this article:   
WANG Yu-Qing, WU Yu-Qin, BIAN Xiu-Fang 2007 Chin. Phys. Lett. 24 2028-2031
Download: PDF(255KB)  
Export: BibTeX | EndNote | Reference Manager | ProCite | RefWorks
Abstract Temperature dependence of viscosity for more than ten kinds of metallic melts is analysed based on viscosity measurements. An obvious turning point is observed on the Arrhenius curves. Since viscosity is one of the physical properties sensitive to structure, its discontinuous change with temperature reveals the possible liquid--liquid structure transition in the metallic melts. Furthermore, an integrated liquid structure transition diagram of the Sn--Bi system is presented. The universality of liquid--liquid structure transition is also discussed simply.
Keywords: 61.25.Mv      61.20.Ne      66.20.+d     
Received: 10 April 2007      Published: 25 June 2007
PACS:  61.25.Mv (Liquid metals and alloys)  
  61.20.Ne (Structure of simple liquids)  
  66.20.+d  
TRENDMD:   
URL:  
https://cpl.iphy.ac.cn/       OR      https://cpl.iphy.ac.cn/Y2007/V24/I7/02028
Service
E-mail this article
E-mail Alert
RSS
Articles by authors
WANG Yu-Qing
WU Yu-Qin
BIAN Xiu-Fang
[1]Katayama Y, Mizatanl T, Utsuml W, Shimomura O and Yamakata M 2000 Nature 403 170
[2]Morishita T 2001 Phys. Rev. Lett. 87 1058701
[3]Zu F Q, Zhu Z G, Gao L J, Zhang B, Shui J P and Liu C S 2001 Phys. Rev. B 64 18023
[4]Zu F Q, Zhu Z G, Gao L J and Qin X B 2002 Phys. Rev. Lett. 89 125505
[5]Aasland S and McMillan P F 1994 Nature 369 633
[6]McMillan P 2000 Nature 403 151
[7]Mishime O and Stanley H E 1998 Nature 392 164
[8]Koga K, Tanaka H and Zeng X C 2000 Nature 408 564
[9]Mitas A C, Patashinski A Z and Shumilo B I 1985 Phys. Lett. 113A 41
[10]Tanaka H 2000 Phys. Rev. E 62 6968
[11]Soper A K and Ricci M A 2000 Phys. Rev. Lett. 84 2881
[12]Glosli J N and Ree F H 1990 Phys. Rev. Lett. 82 4659
[13]Raty J Y, Gaspard J P, Bihan T L, Mazouar M and Bionducci M 1999 J. Phys. Condens. Matter 11 10243
[14]Zu F Q, Guo L J, Zhu Z G. and Feng Y 2002 Chin. Phys.Lett. 19 94
[15]Zu F Q, Zhu Z G, Zhang B, Feng Y, and Shui J P 2001 J. Phys:Condens. Matter 13 11435
[16]Poole P H, Grande T, Angell C A and McMillan P F 1997 Science 275 322
[17]Angell C A, Ngci K L, Mckenna G B, McMillan P F and Martin S W 2000 J. Appl. Phys. 88 3113
[18]Wang Y Q, Wu Y Q, Liu J T and Bian X F 2006 Chin. Phys. Lett. 23 2513
[19]Li H 2004 J. Phys. Chem. B 108 5438
[20]Xue X Y, Bian X F, Geng H X and Qin X B 2003 Mater. Sci.Engin. A 363 134
[21] Wang L, Bian X F and Liu J T 2004 Phys. Lett. A 326429
[22] Wang L and Liu J T 2004 Phys. Lett. A 328 241
[23] Anderson P W 1995 Science 267 1615
[24] Sokolov A P 1996 Science 273 1675
Related articles from Frontiers Journals
[1] DENG Yan-Hong, YE Chao**, YUAN Yuan, LIU Hui-Min, CUI Jin . Effect of the Viscosity of Silicone Oil on the Aggregation Behavior of C:F Clusters on a Silicone Oil Liquid Substrate[J]. Chin. Phys. Lett., 2011, 28(4): 2028-2031
[2] ZHOU Yong-Zhi, LI Mei, GENG Hao-Ran**, YANG Zhong-Xi, SUN Chun-Jing . Hurst's Exponent Determination for Radial Distribution Functions of In, Sn and In-40 wt%Sn Melt[J]. Chin. Phys. Lett., 2011, 28(12): 2028-2031
[3] WANG Dan, PENG Hong-Yan, XU Xiao-Yu, CHEN Bao-Ling, WU Chun-Lei, SUN Min-Hua. Strong-Superstrong Transition in Glass Transition of Metallic Glass[J]. Chin. Phys. Lett., 2010, 27(3): 2028-2031
[4] ZU Fang-Qiu, YU Jin, XU Wei, ZHANG Yan, YANG Hui-Zhen. Reversibility of Temperature-Induced Liquid Transition in Pb26Sn42Bi32 Melt: Experimental Evidence with Electrical Property[J]. Chin. Phys. Lett., 2008, 25(4): 2028-2031
[5] LI Xian-Fen, CHEN Hong-Sheng, ZU Fang-Qiu, CHEN Zhi-Hao, SUN Qi-Qiang, GUO Lei-Lei. Kinetics of Liquid Structure Transition of Sn--(40wt%)Bi Melt[J]. Chin. Phys. Lett., 2008, 25(1): 2028-2031
[6] WANG Li, ZHANG Yan-Ning, MAO Xiu-Ming, PENG Chuan-Xiao. Formation of NiZr2 Binary Metallic Glass: Experimental and Molecular Dynamics Analyses[J]. Chin. Phys. Lett., 2007, 24(8): 2028-2031
[7] WANG Hai-Peng, CHANG Jian, LUO Bing-Chi, WEI Bing-Bo. Determination of the Surface Tension of Liquid Fe 77.5 Cu13Mo 9.5 Ternary Monotectic Alloy[J]. Chin. Phys. Lett., 2007, 24(2): 2028-2031
[8] Iskender AKKURT. Effective Atomic Numbers for Fe--Mn Alloy Using Transmission Experiment[J]. Chin. Phys. Lett., 2007, 24(10): 2028-2031
[9] WANG Yu-Qing, WU Yu-Qin, LIU Jian-Tong, BIAN Xiu-Fang. Discontinuous Structural Phase Transition Behaviour in Multiple Component Alloy Melts[J]. Chin. Phys. Lett., 2006, 23(9): 2028-2031
[10] BIAN Xiu-Fang, SUN Bao-An, HU Li-Na. Medium-Range Order Structure and Fragility of Superheated Melts of Amorphous CuHf Alloys[J]. Chin. Phys. Lett., 2006, 23(7): 2028-2031
[11] SUN Yong-Li, SUN Min-Hua, LI Jia-Yun, WANG Ai-Ping, MA Cong-Xiao, CHENG Wei-Dong, LIU Fang. Molecular Dynamics Simulation of Cage Effect in the Glass Transition of Argon[J]. Chin. Phys. Lett., 2006, 23(10): 2028-2031
[12] ZHAO Gang, LIU Chang-Song, ZHU Zhen-Gang. Ab Initio Molecular Dynamics Simulations on Structural Properties of[J]. Chin. Phys. Lett., 2005, 22(8): 2028-2031
[13] WU Ai-Qing, GUO Li-Jun, LIU Chang-Song, ZHU Zhen-Gang. Structural Characteristics of Liquid Sn[J]. Chin. Phys. Lett., 2005, 22(8): 2028-2031
[14] SUN Min-Hua, WU Zhong-Hua, LIU Guang-Rong, CHEN Xing, CHEN Zhong-Jun. Nanoscale Inhomogeneities in the Glass Transition of Zr41.2Ti13.8Cu12.5Ni10Be22.5 Bulk Metallic Glass[J]. Chin. Phys. Lett., 2005, 22(3): 2028-2031
[15] BIAN Xiu-Fang, ZHANG Jing-Xiang, JIA Yu-Bo, SUN Min-Hua. Viscosity Characteristic in Metallic Melts with Medium/Short-Range Order Structures[J]. Chin. Phys. Lett., 2005, 22(3): 2028-2031
Viewed
Full text


Abstract