Chin. Phys. Lett.  2007, Vol. 24 Issue (4): 1013-1016    DOI:
Original Articles |
Phase Transition Kinetics in Bi3NbO7 Evaluated by in situ Isothermal Conductivity Measurements
WANG Xian-Ping;CHENG Zhi-Jun;FANG Qian-Feng
Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031
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WANG Xian-Ping, CHENG Zhi-Jun, FANG Qian-Feng 2007 Chin. Phys. Lett. 24 1013-1016
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Abstract Kinetics of phase transformation from pseudocubic to tetragonal phase
in Bi3NbO7 solid solution is studied by using the ac impedance method under isothermal conditions. Conductivity of the investigated compound is used to characterize the kinetic process of the transition. The Avrami exponent and the activation energy of phase transition are around 1.5 and 3.5eV, respectively. These kinetic parameters reveal that the pseudocubic-tetragonal transition in Bi3NbO7 belongs to a three-dimensional diffusion-controlled
growth with zero nucleation rate.
Keywords: 64.70.Kb      66.10.Ed     
Received: 21 December 2006      Published: 26 March 2007
PACS:  64.70.Kb  
  66.10.Ed (Ionic conduction)  
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https://cpl.iphy.ac.cn/       OR      https://cpl.iphy.ac.cn/Y2007/V24/I4/01013
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WANG Xian-Ping
CHENG Zhi-Jun
FANG Qian-Feng
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